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4′-Methyl-14′,19′-dioxa-4′-azaspiro[acenaphthylene-1,5′-tetracyclo[18.4.0.0(2,6).0(8,13)]tetracosane]-1′(24′),8′,10′,12′,20′,22′-hexaene-2,7′(1H)-dione
In the title compound, C(33)H(29)NO(4), the acenaphthylene ring system is essentially planar (r.m.s. deviation = 0.0290 Å). The pyrrolidine ring adopts a C-envelope conformation with a C atom displaced by 0.671 (2) Å from the mean-plane formed by the remaining ring atoms. The pyrrolidine ring is fu...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588946/ https://www.ncbi.nlm.nih.gov/pubmed/23476182 http://dx.doi.org/10.1107/S1600536812046144 |
Sumario: | In the title compound, C(33)H(29)NO(4), the acenaphthylene ring system is essentially planar (r.m.s. deviation = 0.0290 Å). The pyrrolidine ring adopts a C-envelope conformation with a C atom displaced by 0.671 (2) Å from the mean-plane formed by the remaining ring atoms. The pyrrolidine ring is fused to acenaphthylene ring system making a dihedral angle of 88.0 (7)°. In the crystal, molecules are linked into R (2) (2)(9) dimers via C—H⋯N and C—H⋯O hydrogen bonds. Two C atoms act as donors to the same O atom acceptor, resulting in the formation of R (2) (1)(7) ring motifs. These two motifs combine to form hydrogen-bonded sheets running along the a- and b-axis directions. |
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