4-Phenyl-1H-1,5-benzodiazepin-2(3H)-one

In the title compound, C(15)H(12)N(2)O, the phenyl ring makes a dihedral angle of 32.45 (9)° with the benzene ring of the 1,5-benzodiazepin-2-one unit. The seven-membered ring adopts a boat conformation with the methyl­ene group as the prow and the fused benzene-ring C atoms as the stern. In the cry...

Descripción completa

Detalles Bibliográficos
Autores principales: Akkurt, Mehmet, Kennedy, Alan R., Younes, Sabry H. H., Mohamed, Shaaban K., Abdelhamid, Antar A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588955/
https://www.ncbi.nlm.nih.gov/pubmed/23476191
http://dx.doi.org/10.1107/S160053681204651X
_version_ 1782261664533446656
author Akkurt, Mehmet
Kennedy, Alan R.
Younes, Sabry H. H.
Mohamed, Shaaban K.
Abdelhamid, Antar A.
author_facet Akkurt, Mehmet
Kennedy, Alan R.
Younes, Sabry H. H.
Mohamed, Shaaban K.
Abdelhamid, Antar A.
author_sort Akkurt, Mehmet
collection PubMed
description In the title compound, C(15)H(12)N(2)O, the phenyl ring makes a dihedral angle of 32.45 (9)° with the benzene ring of the 1,5-benzodiazepin-2-one unit. The seven-membered ring adopts a boat conformation with the methyl­ene group as the prow and the fused benzene-ring C atoms as the stern. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. The dimers are further linked by C—H⋯O hydrogen bonds, so forming a column along the a-axis direction.
format Online
Article
Text
id pubmed-3588955
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35889552013-03-08 4-Phenyl-1H-1,5-benzodiazepin-2(3H)-one Akkurt, Mehmet Kennedy, Alan R. Younes, Sabry H. H. Mohamed, Shaaban K. Abdelhamid, Antar A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(12)N(2)O, the phenyl ring makes a dihedral angle of 32.45 (9)° with the benzene ring of the 1,5-benzodiazepin-2-one unit. The seven-membered ring adopts a boat conformation with the methyl­ene group as the prow and the fused benzene-ring C atoms as the stern. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. The dimers are further linked by C—H⋯O hydrogen bonds, so forming a column along the a-axis direction. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588955/ /pubmed/23476191 http://dx.doi.org/10.1107/S160053681204651X Text en © Akkurt et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Kennedy, Alan R.
Younes, Sabry H. H.
Mohamed, Shaaban K.
Abdelhamid, Antar A.
4-Phenyl-1H-1,5-benzodiazepin-2(3H)-one
title 4-Phenyl-1H-1,5-benzodiazepin-2(3H)-one
title_full 4-Phenyl-1H-1,5-benzodiazepin-2(3H)-one
title_fullStr 4-Phenyl-1H-1,5-benzodiazepin-2(3H)-one
title_full_unstemmed 4-Phenyl-1H-1,5-benzodiazepin-2(3H)-one
title_short 4-Phenyl-1H-1,5-benzodiazepin-2(3H)-one
title_sort 4-phenyl-1h-1,5-benzodiazepin-2(3h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588955/
https://www.ncbi.nlm.nih.gov/pubmed/23476191
http://dx.doi.org/10.1107/S160053681204651X
work_keys_str_mv AT akkurtmehmet 4phenyl1h15benzodiazepin23hone
AT kennedyalanr 4phenyl1h15benzodiazepin23hone
AT younessabryhh 4phenyl1h15benzodiazepin23hone
AT mohamedshaabank 4phenyl1h15benzodiazepin23hone
AT abdelhamidantara 4phenyl1h15benzodiazepin23hone

Ejemplares similares