4-Amino­pyridinium 2-chloro-4-nitro­benzoate monohydrate

In the title hydrated mol­ecular salt, C(5)H(7)N(2) (+)·C(7)H(3)ClNO(4) (−)·H(2)O, the ions and water mol­ecules assemble into ribbons of R (6) (5)(22) rings along the c axis via O(water)—H⋯O(−), N(+)—H⋯O(water) and N—H⋯O(−) hydrogen bonds. N—H⋯O(−) hydrogen bonds connect adjacent ribbons along the...

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Detalles Bibliográficos
Autores principales: Savig, Kelsey L., Lemmerer, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588959/
https://www.ncbi.nlm.nih.gov/pubmed/23476195
http://dx.doi.org/10.1107/S1600536812046077
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author Savig, Kelsey L.
Lemmerer, Andreas
author_facet Savig, Kelsey L.
Lemmerer, Andreas
author_sort Savig, Kelsey L.
collection PubMed
description In the title hydrated mol­ecular salt, C(5)H(7)N(2) (+)·C(7)H(3)ClNO(4) (−)·H(2)O, the ions and water mol­ecules assemble into ribbons of R (6) (5)(22) rings along the c axis via O(water)—H⋯O(−), N(+)—H⋯O(water) and N—H⋯O(−) hydrogen bonds. N—H⋯O(−) hydrogen bonds connect adjacent ribbons along the c-axis direction via R (4) (4)(12) rings, forming hydrogen-bonded layers. The CO(2) and NO(2) groups make dihedral angles of 81.8 (2) and 1.4 (2)°, respectively, with the ring in the anion.
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spelling pubmed-35889592013-03-08 4-Amino­pyridinium 2-chloro-4-nitro­benzoate monohydrate Savig, Kelsey L. Lemmerer, Andreas Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated mol­ecular salt, C(5)H(7)N(2) (+)·C(7)H(3)ClNO(4) (−)·H(2)O, the ions and water mol­ecules assemble into ribbons of R (6) (5)(22) rings along the c axis via O(water)—H⋯O(−), N(+)—H⋯O(water) and N—H⋯O(−) hydrogen bonds. N—H⋯O(−) hydrogen bonds connect adjacent ribbons along the c-axis direction via R (4) (4)(12) rings, forming hydrogen-bonded layers. The CO(2) and NO(2) groups make dihedral angles of 81.8 (2) and 1.4 (2)°, respectively, with the ring in the anion. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588959/ /pubmed/23476195 http://dx.doi.org/10.1107/S1600536812046077 Text en © Savig and Lemmerer 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Savig, Kelsey L.
Lemmerer, Andreas
4-Amino­pyridinium 2-chloro-4-nitro­benzoate monohydrate
title 4-Amino­pyridinium 2-chloro-4-nitro­benzoate monohydrate
title_full 4-Amino­pyridinium 2-chloro-4-nitro­benzoate monohydrate
title_fullStr 4-Amino­pyridinium 2-chloro-4-nitro­benzoate monohydrate
title_full_unstemmed 4-Amino­pyridinium 2-chloro-4-nitro­benzoate monohydrate
title_short 4-Amino­pyridinium 2-chloro-4-nitro­benzoate monohydrate
title_sort 4-amino­pyridinium 2-chloro-4-nitro­benzoate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588959/
https://www.ncbi.nlm.nih.gov/pubmed/23476195
http://dx.doi.org/10.1107/S1600536812046077
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