N-(4-Amino­pyrimidin-5-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide

In the title compound, C(18)H(18)N(4)O(4)S(2), the mean planes passing through the tosyl benzene rings form dihedral angles of 48.42 (9) and 15.1 (1)° with the amino­pyrimidine ring. In the crystal, mol­ecules associate via N—H⋯N and N—H⋯O hydrogen bonds, forming extended hydrogen-bonded sheets that...

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Detalles Bibliográficos
Autores principales: Taher, Abu, Smith, Vincent J
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588960/
https://www.ncbi.nlm.nih.gov/pubmed/23476196
http://dx.doi.org/10.1107/S1600536812046442
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author Taher, Abu
Smith, Vincent J
author_facet Taher, Abu
Smith, Vincent J
author_sort Taher, Abu
collection PubMed
description In the title compound, C(18)H(18)N(4)O(4)S(2), the mean planes passing through the tosyl benzene rings form dihedral angles of 48.42 (9) and 15.1 (1)° with the amino­pyrimidine ring. In the crystal, mol­ecules associate via N—H⋯N and N—H⋯O hydrogen bonds, forming extended hydrogen-bonded sheets that lie parallel to the bc plane. The N—H⋯N hydrogen bonds propagate along the b-axis direction, while the N—H⋯O hydrogen bonds propagate along the c-axis direction.
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spelling pubmed-35889602013-03-08 N-(4-Amino­pyrimidin-5-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide Taher, Abu Smith, Vincent J Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(18)N(4)O(4)S(2), the mean planes passing through the tosyl benzene rings form dihedral angles of 48.42 (9) and 15.1 (1)° with the amino­pyrimidine ring. In the crystal, mol­ecules associate via N—H⋯N and N—H⋯O hydrogen bonds, forming extended hydrogen-bonded sheets that lie parallel to the bc plane. The N—H⋯N hydrogen bonds propagate along the b-axis direction, while the N—H⋯O hydrogen bonds propagate along the c-axis direction. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588960/ /pubmed/23476196 http://dx.doi.org/10.1107/S1600536812046442 Text en © Taher and Smith 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Taher, Abu
Smith, Vincent J
N-(4-Amino­pyrimidin-5-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide
title N-(4-Amino­pyrimidin-5-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide
title_full N-(4-Amino­pyrimidin-5-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide
title_fullStr N-(4-Amino­pyrimidin-5-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide
title_full_unstemmed N-(4-Amino­pyrimidin-5-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide
title_short N-(4-Amino­pyrimidin-5-yl)-4-methyl-N-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide
title_sort n-(4-amino­pyrimidin-5-yl)-4-methyl-n-(4-methyl­phenyl­sulfon­yl)benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588960/
https://www.ncbi.nlm.nih.gov/pubmed/23476196
http://dx.doi.org/10.1107/S1600536812046442
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