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1-(2-Amino-6-methylpyrimidin-4-yl)-N,N-dimethylpiperidin-4-aminium chloride
In the title molecular salt, C(12)H(22)N(5) (+)·Cl(−), the cation is protonated at the dimethyl-substituted tertiary N atom. The piperidine ring adopts a chair conformation with the exocyclic N—C bond in an equatorial orientation. The dihedral angle between the piperidine ring (all atoms) and the p...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588967/ https://www.ncbi.nlm.nih.gov/pubmed/23476203 http://dx.doi.org/10.1107/S1600536812046533 |
Sumario: | In the title molecular salt, C(12)H(22)N(5) (+)·Cl(−), the cation is protonated at the dimethyl-substituted tertiary N atom. The piperidine ring adopts a chair conformation with the exocyclic N—C bond in an equatorial orientation. The dihedral angle between the piperidine ring (all atoms) and the pyrimidine ring is 14.00 (1)°. In the crystal, the ions are connected by N—H⋯N hydrogen bonds, forming inversion dimers, which are further connected by N—H⋯Cl hydrogen bonds. Aromatic π–π stacking interactions [centroid–centroid separation = 3.4790 (9) Å] are also observed in the structure. |
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