Cargando…

1-(2-Amino-6-methyl­pyrimidin-4-yl)-N,N-dimethyl­piperidin-4-aminium chloride

In the title mol­ecular salt, C(12)H(22)N(5) (+)·Cl(−), the cation is protonated at the dimethyl-substituted tertiary N atom. The piperidine ring adopts a chair conformation with the exocyclic N—C bond in an equatorial orientation. The dihedral angle between the piperidine ring (all atoms) and the p...

Descripción completa

Detalles Bibliográficos
Autores principales: Sreenivasa, S., ManojKumar, K.E., Suchetan, P.A., Srinivasan, T., Palakshamurthy, B. S., Velmurgan, D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588967/
https://www.ncbi.nlm.nih.gov/pubmed/23476203
http://dx.doi.org/10.1107/S1600536812046533
Descripción
Sumario:In the title mol­ecular salt, C(12)H(22)N(5) (+)·Cl(−), the cation is protonated at the dimethyl-substituted tertiary N atom. The piperidine ring adopts a chair conformation with the exocyclic N—C bond in an equatorial orientation. The dihedral angle between the piperidine ring (all atoms) and the pyrimidine ring is 14.00 (1)°. In the crystal, the ions are connected by N—H⋯N hydrogen bonds, forming inversion dimers, which are further connected by N—H⋯Cl hydrogen bonds. Aromatic π–π stacking inter­actions [centroid–centroid separation = 3.4790 (9) Å] are also observed in the structure.