2-Amino-4,6-dimethyl­pyrimidin-1-ium chloride

In the title compound, C(6)H(10)N(3) (+)·Cl(−), the cation is essentially planar with an r.m.s. deviations of the fitted atoms of 0.008 Å. In the crystal, adjacent ions are linked by weak N—H⋯Cl hydrogen bonds involving the pyrimidine and amine N atoms, forming a three-dimensional network. C—H⋯π int...

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Detalles Bibliográficos
Autores principales: Hu, Hui-Ling, Yeh, Chun-Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588968/
https://www.ncbi.nlm.nih.gov/pubmed/23476204
http://dx.doi.org/10.1107/S1600536812046569
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author Hu, Hui-Ling
Yeh, Chun-Wei
author_facet Hu, Hui-Ling
Yeh, Chun-Wei
author_sort Hu, Hui-Ling
collection PubMed
description In the title compound, C(6)H(10)N(3) (+)·Cl(−), the cation is essentially planar with an r.m.s. deviations of the fitted atoms of 0.008 Å. In the crystal, adjacent ions are linked by weak N—H⋯Cl hydrogen bonds involving the pyrimidine and amine N atoms, forming a three-dimensional network. C—H⋯π inter­actions between the methyl and pyrimidine groups and π–π stacking [centroid–centroid distance = 3.474 (1) Å] between parallel pyrimidine ring systems are also observed.
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spelling pubmed-35889682013-03-08 2-Amino-4,6-dimethyl­pyrimidin-1-ium chloride Hu, Hui-Ling Yeh, Chun-Wei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(10)N(3) (+)·Cl(−), the cation is essentially planar with an r.m.s. deviations of the fitted atoms of 0.008 Å. In the crystal, adjacent ions are linked by weak N—H⋯Cl hydrogen bonds involving the pyrimidine and amine N atoms, forming a three-dimensional network. C—H⋯π inter­actions between the methyl and pyrimidine groups and π–π stacking [centroid–centroid distance = 3.474 (1) Å] between parallel pyrimidine ring systems are also observed. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588968/ /pubmed/23476204 http://dx.doi.org/10.1107/S1600536812046569 Text en © Hu and Yeh 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hu, Hui-Ling
Yeh, Chun-Wei
2-Amino-4,6-dimethyl­pyrimidin-1-ium chloride
title 2-Amino-4,6-dimethyl­pyrimidin-1-ium chloride
title_full 2-Amino-4,6-dimethyl­pyrimidin-1-ium chloride
title_fullStr 2-Amino-4,6-dimethyl­pyrimidin-1-ium chloride
title_full_unstemmed 2-Amino-4,6-dimethyl­pyrimidin-1-ium chloride
title_short 2-Amino-4,6-dimethyl­pyrimidin-1-ium chloride
title_sort 2-amino-4,6-dimethyl­pyrimidin-1-ium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588968/
https://www.ncbi.nlm.nih.gov/pubmed/23476204
http://dx.doi.org/10.1107/S1600536812046569
work_keys_str_mv AT huhuiling 2amino46dimethylpyrimidin1iumchloride
AT yehchunwei 2amino46dimethylpyrimidin1iumchloride

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