Dicyclo­hexyl­bis­(naphthalen-1-ylmeth­yl)phospho­nium chloride chloro­form disolvate

In the title solvated phosphonium salt, C(34)H(40)P(+)·Cl(−)·2CHCl(3), the two cyclo­hexyl and two 1-naphthyl­methyl groups at the P atom are in a distorted tetra­hedral arrangement [105.26 (6)–113.35 (6)°]. Both cyclo­hexyl rings adopt a chair conformation. The dihedral angle between the naphthyl r...

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Autores principales: Gowrisankar, Saravanan, Neumann, Helfried, Spannenberg, Anke, Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588969/
https://www.ncbi.nlm.nih.gov/pubmed/23476205
http://dx.doi.org/10.1107/S1600536812046661
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author Gowrisankar, Saravanan
Neumann, Helfried
Spannenberg, Anke
Beller, Matthias
author_facet Gowrisankar, Saravanan
Neumann, Helfried
Spannenberg, Anke
Beller, Matthias
author_sort Gowrisankar, Saravanan
collection PubMed
description In the title solvated phosphonium salt, C(34)H(40)P(+)·Cl(−)·2CHCl(3), the two cyclo­hexyl and two 1-naphthyl­methyl groups at the P atom are in a distorted tetra­hedral arrangement [105.26 (6)–113.35 (6)°]. Both cyclo­hexyl rings adopt a chair conformation. The dihedral angle between the naphthyl ring systems is 74.08 (3)°.
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spelling pubmed-35889692013-03-08 Dicyclo­hexyl­bis­(naphthalen-1-ylmeth­yl)phospho­nium chloride chloro­form disolvate Gowrisankar, Saravanan Neumann, Helfried Spannenberg, Anke Beller, Matthias Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title solvated phosphonium salt, C(34)H(40)P(+)·Cl(−)·2CHCl(3), the two cyclo­hexyl and two 1-naphthyl­methyl groups at the P atom are in a distorted tetra­hedral arrangement [105.26 (6)–113.35 (6)°]. Both cyclo­hexyl rings adopt a chair conformation. The dihedral angle between the naphthyl ring systems is 74.08 (3)°. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588969/ /pubmed/23476205 http://dx.doi.org/10.1107/S1600536812046661 Text en © Gowrisankar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowrisankar, Saravanan
Neumann, Helfried
Spannenberg, Anke
Beller, Matthias
Dicyclo­hexyl­bis­(naphthalen-1-ylmeth­yl)phospho­nium chloride chloro­form disolvate
title Dicyclo­hexyl­bis­(naphthalen-1-ylmeth­yl)phospho­nium chloride chloro­form disolvate
title_full Dicyclo­hexyl­bis­(naphthalen-1-ylmeth­yl)phospho­nium chloride chloro­form disolvate
title_fullStr Dicyclo­hexyl­bis­(naphthalen-1-ylmeth­yl)phospho­nium chloride chloro­form disolvate
title_full_unstemmed Dicyclo­hexyl­bis­(naphthalen-1-ylmeth­yl)phospho­nium chloride chloro­form disolvate
title_short Dicyclo­hexyl­bis­(naphthalen-1-ylmeth­yl)phospho­nium chloride chloro­form disolvate
title_sort dicyclo­hexyl­bis­(naphthalen-1-ylmeth­yl)phospho­nium chloride chloro­form disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588969/
https://www.ncbi.nlm.nih.gov/pubmed/23476205
http://dx.doi.org/10.1107/S1600536812046661
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