2-Hy­droxy-5-[(E)-2-methyl­benzyl­idene]-8-(2-methyl­phen­yl)-9-phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(20),12,14,16,18-pentaen-6-one

In the title compound, C(40)H(34)N(2)O(2), the central piperidine ring adopts a half-chair conformation and the fused pyrrolidine rings adopt twisted envelope (with the C atom bearing the methylphenyl ring as the flap atom) and envelope (with the C atom bound to the N atom, common to the pyridinone...

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Detalles Bibliográficos
Autores principales: Almansour, Abdulrahman I., Kumar, Raju Suresh, Arumugam, Natarajan, Osman, Hasnah, Suresh, J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588971/
https://www.ncbi.nlm.nih.gov/pubmed/23476207
http://dx.doi.org/10.1107/S160053681204648X
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author Almansour, Abdulrahman I.
Kumar, Raju Suresh
Arumugam, Natarajan
Osman, Hasnah
Suresh, J.
author_facet Almansour, Abdulrahman I.
Kumar, Raju Suresh
Arumugam, Natarajan
Osman, Hasnah
Suresh, J.
author_sort Almansour, Abdulrahman I.
collection PubMed
description In the title compound, C(40)H(34)N(2)O(2), the central piperidine ring adopts a half-chair conformation and the fused pyrrolidine rings adopt twisted envelope (with the C atom bearing the methylphenyl ring as the flap atom) and envelope (with the C atom bound to the N atom, common to the pyridinone and pyrrolidine rings being the flap atom) conformations. The mol­ecular structure features weak intra­molecular N—H⋯O and C—H⋯O inter­actions. In the crystal, O—H⋯O hydrogen bonds generate a C(7) chain along the b-axis direction. C—H⋯O inter­actions also occur.
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spelling pubmed-35889712013-03-08 2-Hy­droxy-5-[(E)-2-methyl­benzyl­idene]-8-(2-methyl­phen­yl)-9-phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(20),12,14,16,18-pentaen-6-one Almansour, Abdulrahman I. Kumar, Raju Suresh Arumugam, Natarajan Osman, Hasnah Suresh, J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(40)H(34)N(2)O(2), the central piperidine ring adopts a half-chair conformation and the fused pyrrolidine rings adopt twisted envelope (with the C atom bearing the methylphenyl ring as the flap atom) and envelope (with the C atom bound to the N atom, common to the pyridinone and pyrrolidine rings being the flap atom) conformations. The mol­ecular structure features weak intra­molecular N—H⋯O and C—H⋯O inter­actions. In the crystal, O—H⋯O hydrogen bonds generate a C(7) chain along the b-axis direction. C—H⋯O inter­actions also occur. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588971/ /pubmed/23476207 http://dx.doi.org/10.1107/S160053681204648X Text en © Almansour et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Almansour, Abdulrahman I.
Kumar, Raju Suresh
Arumugam, Natarajan
Osman, Hasnah
Suresh, J.
2-Hy­droxy-5-[(E)-2-methyl­benzyl­idene]-8-(2-methyl­phen­yl)-9-phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(20),12,14,16,18-pentaen-6-one
title 2-Hy­droxy-5-[(E)-2-methyl­benzyl­idene]-8-(2-methyl­phen­yl)-9-phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(20),12,14,16,18-pentaen-6-one
title_full 2-Hy­droxy-5-[(E)-2-methyl­benzyl­idene]-8-(2-methyl­phen­yl)-9-phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(20),12,14,16,18-pentaen-6-one
title_fullStr 2-Hy­droxy-5-[(E)-2-methyl­benzyl­idene]-8-(2-methyl­phen­yl)-9-phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(20),12,14,16,18-pentaen-6-one
title_full_unstemmed 2-Hy­droxy-5-[(E)-2-methyl­benzyl­idene]-8-(2-methyl­phen­yl)-9-phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(20),12,14,16,18-pentaen-6-one
title_short 2-Hy­droxy-5-[(E)-2-methyl­benzyl­idene]-8-(2-methyl­phen­yl)-9-phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(20),12,14,16,18-pentaen-6-one
title_sort 2-hy­droxy-5-[(e)-2-methyl­benzyl­idene]-8-(2-methyl­phen­yl)-9-phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(20),12,14,16,18-pentaen-6-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588971/
https://www.ncbi.nlm.nih.gov/pubmed/23476207
http://dx.doi.org/10.1107/S160053681204648X
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