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4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene](phen­yl)meth­yl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate

In the title compound, C(23)H(18)N(6)O(5)·C(2)H(6)O, all three benzene rings lie in an approximate plane [maximum deviation = 0.2688 (16) Å] that makes an angle of 53.56 (3)° with the plane of the pyrazolone ring. Intra­molecular N—H⋯O hydrogen bonds occur. In the crystal, the ethanol solvent mol­ec...

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Detalles Bibliográficos
Autores principales: Idemudia, Omoruyi G., Sadimenko, Alexander P., Hosten, Eric C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588976/
https://www.ncbi.nlm.nih.gov/pubmed/23476212
http://dx.doi.org/10.1107/S1600536812044935
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author Idemudia, Omoruyi G.
Sadimenko, Alexander P.
Hosten, Eric C.
author_facet Idemudia, Omoruyi G.
Sadimenko, Alexander P.
Hosten, Eric C.
author_sort Idemudia, Omoruyi G.
collection PubMed
description In the title compound, C(23)H(18)N(6)O(5)·C(2)H(6)O, all three benzene rings lie in an approximate plane [maximum deviation = 0.2688 (16) Å] that makes an angle of 53.56 (3)° with the plane of the pyrazolone ring. Intra­molecular N—H⋯O hydrogen bonds occur. In the crystal, the ethanol solvent mol­ecule links adjacent mol­ecules through N—H⋯O—H⋯O hydrogen bonds, leading to an infinite chain along the c-axis direction. The ethyl group of the ethanol solvent mol­ecule is disordered over two set of sites in a 0.762 (5):0.238 (5) ratio.
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spelling pubmed-35889762013-03-08 4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene](phen­yl)meth­yl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate Idemudia, Omoruyi G. Sadimenko, Alexander P. Hosten, Eric C. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(18)N(6)O(5)·C(2)H(6)O, all three benzene rings lie in an approximate plane [maximum deviation = 0.2688 (16) Å] that makes an angle of 53.56 (3)° with the plane of the pyrazolone ring. Intra­molecular N—H⋯O hydrogen bonds occur. In the crystal, the ethanol solvent mol­ecule links adjacent mol­ecules through N—H⋯O—H⋯O hydrogen bonds, leading to an infinite chain along the c-axis direction. The ethyl group of the ethanol solvent mol­ecule is disordered over two set of sites in a 0.762 (5):0.238 (5) ratio. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588976/ /pubmed/23476212 http://dx.doi.org/10.1107/S1600536812044935 Text en © Idemudia et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Idemudia, Omoruyi G.
Sadimenko, Alexander P.
Hosten, Eric C.
4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene](phen­yl)meth­yl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate
title 4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene](phen­yl)meth­yl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate
title_full 4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene](phen­yl)meth­yl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate
title_fullStr 4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene](phen­yl)meth­yl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate
title_full_unstemmed 4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene](phen­yl)meth­yl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate
title_short 4-{[2-(2,4-Dinitro­phen­yl)hydrazinyl­idene](phen­yl)meth­yl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate
title_sort 4-{[2-(2,4-dinitro­phen­yl)hydrazinyl­idene](phen­yl)meth­yl}-5-methyl-2-phenyl-1h-pyrazol-3(2h)-one ethanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588976/
https://www.ncbi.nlm.nih.gov/pubmed/23476212
http://dx.doi.org/10.1107/S1600536812044935
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