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4-{[2-(2,4-Dinitrophenyl)hydrazinylidene](phenyl)methyl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate
In the title compound, C(23)H(18)N(6)O(5)·C(2)H(6)O, all three benzene rings lie in an approximate plane [maximum deviation = 0.2688 (16) Å] that makes an angle of 53.56 (3)° with the plane of the pyrazolone ring. Intramolecular N—H⋯O hydrogen bonds occur. In the crystal, the ethanol solvent molec...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588976/ https://www.ncbi.nlm.nih.gov/pubmed/23476212 http://dx.doi.org/10.1107/S1600536812044935 |
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author | Idemudia, Omoruyi G. Sadimenko, Alexander P. Hosten, Eric C. |
author_facet | Idemudia, Omoruyi G. Sadimenko, Alexander P. Hosten, Eric C. |
author_sort | Idemudia, Omoruyi G. |
collection | PubMed |
description | In the title compound, C(23)H(18)N(6)O(5)·C(2)H(6)O, all three benzene rings lie in an approximate plane [maximum deviation = 0.2688 (16) Å] that makes an angle of 53.56 (3)° with the plane of the pyrazolone ring. Intramolecular N—H⋯O hydrogen bonds occur. In the crystal, the ethanol solvent molecule links adjacent molecules through N—H⋯O—H⋯O hydrogen bonds, leading to an infinite chain along the c-axis direction. The ethyl group of the ethanol solvent molecule is disordered over two set of sites in a 0.762 (5):0.238 (5) ratio. |
format | Online Article Text |
id | pubmed-3588976 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35889762013-03-08 4-{[2-(2,4-Dinitrophenyl)hydrazinylidene](phenyl)methyl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate Idemudia, Omoruyi G. Sadimenko, Alexander P. Hosten, Eric C. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(18)N(6)O(5)·C(2)H(6)O, all three benzene rings lie in an approximate plane [maximum deviation = 0.2688 (16) Å] that makes an angle of 53.56 (3)° with the plane of the pyrazolone ring. Intramolecular N—H⋯O hydrogen bonds occur. In the crystal, the ethanol solvent molecule links adjacent molecules through N—H⋯O—H⋯O hydrogen bonds, leading to an infinite chain along the c-axis direction. The ethyl group of the ethanol solvent molecule is disordered over two set of sites in a 0.762 (5):0.238 (5) ratio. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588976/ /pubmed/23476212 http://dx.doi.org/10.1107/S1600536812044935 Text en © Idemudia et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Idemudia, Omoruyi G. Sadimenko, Alexander P. Hosten, Eric C. 4-{[2-(2,4-Dinitrophenyl)hydrazinylidene](phenyl)methyl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate |
title | 4-{[2-(2,4-Dinitrophenyl)hydrazinylidene](phenyl)methyl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate |
title_full | 4-{[2-(2,4-Dinitrophenyl)hydrazinylidene](phenyl)methyl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate |
title_fullStr | 4-{[2-(2,4-Dinitrophenyl)hydrazinylidene](phenyl)methyl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate |
title_full_unstemmed | 4-{[2-(2,4-Dinitrophenyl)hydrazinylidene](phenyl)methyl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate |
title_short | 4-{[2-(2,4-Dinitrophenyl)hydrazinylidene](phenyl)methyl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate |
title_sort | 4-{[2-(2,4-dinitrophenyl)hydrazinylidene](phenyl)methyl}-5-methyl-2-phenyl-1h-pyrazol-3(2h)-one ethanol monosolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588976/ https://www.ncbi.nlm.nih.gov/pubmed/23476212 http://dx.doi.org/10.1107/S1600536812044935 |
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