Methyl 2-(3-chloro­benzamido)­benzoate

In the mol­ecule of the title compound, C(15)H(12)ClNO(3), the chloro­benzamide and benzoate units are almost co-planar, with a dihedral angle between the six-membered rings of 2.99 (10)°. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, each mol­ecule is linked to a symmetry-equivalen...

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Autores principales: Ouahrouch, Abdelaaziz, Taourirte, Moha, Lazrek, Hassan B., El Azhari, Mohamed, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588991/
https://www.ncbi.nlm.nih.gov/pubmed/23476227
http://dx.doi.org/10.1107/S1600536812046934
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author Ouahrouch, Abdelaaziz
Taourirte, Moha
Lazrek, Hassan B.
El Azhari, Mohamed
Saadi, Mohamed
El Ammari, Lahcen
author_facet Ouahrouch, Abdelaaziz
Taourirte, Moha
Lazrek, Hassan B.
El Azhari, Mohamed
Saadi, Mohamed
El Ammari, Lahcen
author_sort Ouahrouch, Abdelaaziz
collection PubMed
description In the mol­ecule of the title compound, C(15)H(12)ClNO(3), the chloro­benzamide and benzoate units are almost co-planar, with a dihedral angle between the six-membered rings of 2.99 (10)°. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, each mol­ecule is linked to a symmetry-equivalent counterpart across a twofold rotation axis by weak C—H⋯O and C—H⋯Cl hydrogen bonds, forming dimers. The packing is stabilized through weak π–π stacking along the b-axis direction, leading to π-stacked columns of inversion-related mol­ecules, with an inter­planar distance of 3.46 (2) Å and a centroid–centroid vector of 3.897 (2) Å.
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spelling pubmed-35889912013-03-08 Methyl 2-(3-chloro­benzamido)­benzoate Ouahrouch, Abdelaaziz Taourirte, Moha Lazrek, Hassan B. El Azhari, Mohamed Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(15)H(12)ClNO(3), the chloro­benzamide and benzoate units are almost co-planar, with a dihedral angle between the six-membered rings of 2.99 (10)°. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, each mol­ecule is linked to a symmetry-equivalent counterpart across a twofold rotation axis by weak C—H⋯O and C—H⋯Cl hydrogen bonds, forming dimers. The packing is stabilized through weak π–π stacking along the b-axis direction, leading to π-stacked columns of inversion-related mol­ecules, with an inter­planar distance of 3.46 (2) Å and a centroid–centroid vector of 3.897 (2) Å. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588991/ /pubmed/23476227 http://dx.doi.org/10.1107/S1600536812046934 Text en © Ouahrouch et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ouahrouch, Abdelaaziz
Taourirte, Moha
Lazrek, Hassan B.
El Azhari, Mohamed
Saadi, Mohamed
El Ammari, Lahcen
Methyl 2-(3-chloro­benzamido)­benzoate
title Methyl 2-(3-chloro­benzamido)­benzoate
title_full Methyl 2-(3-chloro­benzamido)­benzoate
title_fullStr Methyl 2-(3-chloro­benzamido)­benzoate
title_full_unstemmed Methyl 2-(3-chloro­benzamido)­benzoate
title_short Methyl 2-(3-chloro­benzamido)­benzoate
title_sort methyl 2-(3-chloro­benzamido)­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588991/
https://www.ncbi.nlm.nih.gov/pubmed/23476227
http://dx.doi.org/10.1107/S1600536812046934
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AT elazharimohamed methyl23chlorobenzamidobenzoate
AT saadimohamed methyl23chlorobenzamidobenzoate
AT elammarilahcen methyl23chlorobenzamidobenzoate

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