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N-(4-Fluoro­benzo­yl)-N′,N′′-diisopropyl­phospho­ric triamide

The asymmetric unit of the title phospho­ric triamide, C(13)H(21)FN(3)O(2)P, consists of two independent mol­ecules. In each mol­ecule, the P=O group and the N—H unit belonging to the C(O)NHP(O) fragment are in a syn conformation with respect to each other. An intra­molecular N—H⋯O hydrogen bond occ...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Tarahhomi, Atekeh, Rheingold, Arnold L., Golen, James A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588995/
https://www.ncbi.nlm.nih.gov/pubmed/23476231
http://dx.doi.org/10.1107/S1600536812046326
Descripción
Sumario:The asymmetric unit of the title phospho­ric triamide, C(13)H(21)FN(3)O(2)P, consists of two independent mol­ecules. In each mol­ecule, the P=O group and the N—H unit belonging to the C(O)NHP(O) fragment are in a syn conformation with respect to each other. An intra­molecular N—H⋯O hydrogen bond occurs in each mol­ecule. The P atom adopts a distorted tetra­hedral environment. The methyl groups of an isopropyl fragment are disordered over two sets of sites with refined occupancies of 0.458 (5) and 0.542 (5). In the crystal, mol­ecules are linked through N—H⋯O(=P) and N—H⋯O(=C) hydrogen bonds into chains along [001].