(Z)-Ethyl 2-chloro-2-[2-(4-methyl­phen­yl)hydrazinyl­idene]acetate

The mol­ecule of the title compound, C(11)H(13)ClN(2)O(2), is approximately planar (r.m.s. deviation = 0.099 Å for non-H atoms) and adopts a Z conformation about the C=N double bond. In the crystal, mol­ecules are linked by N—H⋯O and C—H⋯O hydrogen bonds to the same O-atom acceptor, forming zigzag c...

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Detalles Bibliográficos
Autores principales: Asiri, Abdullah M., Arshad, Muhammad Nadeem, Zayed, Mohie E. M., Alamry, Khalid A., Bokhari, Tanveer Hussain
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589004/
https://www.ncbi.nlm.nih.gov/pubmed/23476240
http://dx.doi.org/10.1107/S1600536812046521
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author Asiri, Abdullah M.
Arshad, Muhammad Nadeem
Zayed, Mohie E. M.
Alamry, Khalid A.
Bokhari, Tanveer Hussain
author_facet Asiri, Abdullah M.
Arshad, Muhammad Nadeem
Zayed, Mohie E. M.
Alamry, Khalid A.
Bokhari, Tanveer Hussain
author_sort Asiri, Abdullah M.
collection PubMed
description The mol­ecule of the title compound, C(11)H(13)ClN(2)O(2), is approximately planar (r.m.s. deviation = 0.099 Å for non-H atoms) and adopts a Z conformation about the C=N double bond. In the crystal, mol­ecules are linked by N—H⋯O and C—H⋯O hydrogen bonds to the same O-atom acceptor, forming zigzag chains propagating along [010]. These inter­actions give rise to R (2) (1)(6) loops.
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spelling pubmed-35890042013-03-08 (Z)-Ethyl 2-chloro-2-[2-(4-methyl­phen­yl)hydrazinyl­idene]acetate Asiri, Abdullah M. Arshad, Muhammad Nadeem Zayed, Mohie E. M. Alamry, Khalid A. Bokhari, Tanveer Hussain Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(11)H(13)ClN(2)O(2), is approximately planar (r.m.s. deviation = 0.099 Å for non-H atoms) and adopts a Z conformation about the C=N double bond. In the crystal, mol­ecules are linked by N—H⋯O and C—H⋯O hydrogen bonds to the same O-atom acceptor, forming zigzag chains propagating along [010]. These inter­actions give rise to R (2) (1)(6) loops. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3589004/ /pubmed/23476240 http://dx.doi.org/10.1107/S1600536812046521 Text en © Asiri et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asiri, Abdullah M.
Arshad, Muhammad Nadeem
Zayed, Mohie E. M.
Alamry, Khalid A.
Bokhari, Tanveer Hussain
(Z)-Ethyl 2-chloro-2-[2-(4-methyl­phen­yl)hydrazinyl­idene]acetate
title (Z)-Ethyl 2-chloro-2-[2-(4-methyl­phen­yl)hydrazinyl­idene]acetate
title_full (Z)-Ethyl 2-chloro-2-[2-(4-methyl­phen­yl)hydrazinyl­idene]acetate
title_fullStr (Z)-Ethyl 2-chloro-2-[2-(4-methyl­phen­yl)hydrazinyl­idene]acetate
title_full_unstemmed (Z)-Ethyl 2-chloro-2-[2-(4-methyl­phen­yl)hydrazinyl­idene]acetate
title_short (Z)-Ethyl 2-chloro-2-[2-(4-methyl­phen­yl)hydrazinyl­idene]acetate
title_sort (z)-ethyl 2-chloro-2-[2-(4-methyl­phen­yl)hydrazinyl­idene]acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589004/
https://www.ncbi.nlm.nih.gov/pubmed/23476240
http://dx.doi.org/10.1107/S1600536812046521
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