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1,3-Dibenzyl-2-(2-chloro­phen­yl)-4-methyl­imidazolidine

In the title compound, C(24)H(25)ClN(2), the methine, methyl­ene and methyl C atoms of the methyl-substituted imidazolidine ring are disordered over two sets of sites with a refined occupancy ratio of 0.834 (4):0.166 (4). Each disordered ring assumes an envelope conformation with an N atom as the fl...

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Autores principales: Rivera, Augusto, Cardenas, Lorena, Ríos-Motta, Jaime, Eigner, Václav, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589010/
https://www.ncbi.nlm.nih.gov/pubmed/23476246
http://dx.doi.org/10.1107/S1600536812047575
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author Rivera, Augusto
Cardenas, Lorena
Ríos-Motta, Jaime
Eigner, Václav
Dušek, Michal
author_facet Rivera, Augusto
Cardenas, Lorena
Ríos-Motta, Jaime
Eigner, Václav
Dušek, Michal
author_sort Rivera, Augusto
collection PubMed
description In the title compound, C(24)H(25)ClN(2), the methine, methyl­ene and methyl C atoms of the methyl-substituted imidazolidine ring are disordered over two sets of sites with a refined occupancy ratio of 0.834 (4):0.166 (4). Each disordered ring assumes an envelope conformation with an N atom as the flap. The pendant benzyl rings are oriented equatorially with respect to the imidazolidine ring. The chloro­phenyl ring is inclined to the mean plane of the four planar atoms of the major component of the imidazolidine ring by 76.27 (12)°. The dihedral angles between the chloro­phenyl ring and the two benzyl rings are 55.31 (9) and 57.50 (8)°; the dihedral angle between these latter rings is 71.59 (9)°. In the crystal, mol­ecules are linked by C—H⋯Cl inter­actions and a number of weak C—H⋯π inter­actions, involving all three aromatic rings, forming a three-dimensional structure.
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spelling pubmed-35890102013-03-08 1,3-Dibenzyl-2-(2-chloro­phen­yl)-4-methyl­imidazolidine Rivera, Augusto Cardenas, Lorena Ríos-Motta, Jaime Eigner, Václav Dušek, Michal Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(25)ClN(2), the methine, methyl­ene and methyl C atoms of the methyl-substituted imidazolidine ring are disordered over two sets of sites with a refined occupancy ratio of 0.834 (4):0.166 (4). Each disordered ring assumes an envelope conformation with an N atom as the flap. The pendant benzyl rings are oriented equatorially with respect to the imidazolidine ring. The chloro­phenyl ring is inclined to the mean plane of the four planar atoms of the major component of the imidazolidine ring by 76.27 (12)°. The dihedral angles between the chloro­phenyl ring and the two benzyl rings are 55.31 (9) and 57.50 (8)°; the dihedral angle between these latter rings is 71.59 (9)°. In the crystal, mol­ecules are linked by C—H⋯Cl inter­actions and a number of weak C—H⋯π inter­actions, involving all three aromatic rings, forming a three-dimensional structure. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3589010/ /pubmed/23476246 http://dx.doi.org/10.1107/S1600536812047575 Text en © Rivera et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rivera, Augusto
Cardenas, Lorena
Ríos-Motta, Jaime
Eigner, Václav
Dušek, Michal
1,3-Dibenzyl-2-(2-chloro­phen­yl)-4-methyl­imidazolidine
title 1,3-Dibenzyl-2-(2-chloro­phen­yl)-4-methyl­imidazolidine
title_full 1,3-Dibenzyl-2-(2-chloro­phen­yl)-4-methyl­imidazolidine
title_fullStr 1,3-Dibenzyl-2-(2-chloro­phen­yl)-4-methyl­imidazolidine
title_full_unstemmed 1,3-Dibenzyl-2-(2-chloro­phen­yl)-4-methyl­imidazolidine
title_short 1,3-Dibenzyl-2-(2-chloro­phen­yl)-4-methyl­imidazolidine
title_sort 1,3-dibenzyl-2-(2-chloro­phen­yl)-4-methyl­imidazolidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589010/
https://www.ncbi.nlm.nih.gov/pubmed/23476246
http://dx.doi.org/10.1107/S1600536812047575
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