2,2′-[1,2-Phenyl­enebis(aza­nedi­yl)]di­aceto­nitrile

The title compound, C(10)H(10)N(4), shows chemical but not crystallographic C (2) symmetry. The two cyano­methyl groups are located in an anti position with respect to the aromatic ring. In the crystal, mol­ecules form parallel ladder-like tapes linked through two N—H⋯N hydrogen bonds. Further weak...

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Detalles Bibliográficos
Autores principales: Rivera, Augusto, Jiménez-Cruz, Leonardo, Maldonado, Mauricio, Kučeráková, Monika, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589011/
https://www.ncbi.nlm.nih.gov/pubmed/23476247
http://dx.doi.org/10.1107/S1600536812047538
Descripción
Sumario:The title compound, C(10)H(10)N(4), shows chemical but not crystallographic C (2) symmetry. The two cyano­methyl groups are located in an anti position with respect to the aromatic ring. In the crystal, mol­ecules form parallel ladder-like tapes linked through two N—H⋯N hydrogen bonds. Further weak intra­molecular N—H⋯N hydrogen bonding is responsible for the elongation of one of the C(aromatic)—N bonds.

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