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2,5-Bis[2-({bis[3-(dimethylazaniumyl)propyl]azaniumyl}methyl)phenyl]-1,3,4-oxadiazole hexakis(perchlorate) sesquihydrate
In the title hydrated salt, C(36)H(66)N(8)O(6+)·6ClO(4) (−)·1.5H(2)O, the asymmetric unit consists of a hexaprotonated [H(6) L](6+) cation, five perchlorate anions in general positions, two on twofold rotation axes (one of which is disordered), and two water molecules of crystallization in general...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589030/ https://www.ncbi.nlm.nih.gov/pubmed/23476266 http://dx.doi.org/10.1107/S1600536812047484 |
Sumario: | In the title hydrated salt, C(36)H(66)N(8)O(6+)·6ClO(4) (−)·1.5H(2)O, the asymmetric unit consists of a hexaprotonated [H(6) L](6+) cation, five perchlorate anions in general positions, two on twofold rotation axes (one of which is disordered), and two water molecules of crystallization in general positions, one of them disordered around a twofold crystallographic axis. In the [H(6) L](6+) cation, two strong intramolecular N—H⋯N hydrogen bonds occur, involving the N atoms of the oxadiazole ring as acceptors and the closest NH(+) groups of each dipropylenetriamine unit. In the crystal, the [H(6) L](6+) cations form channels along the a-axis direction, in which the perchlorate counter-ions and the water molecules are lodged. The crystal packing features a network of N—H⋯O and O—H⋯O hydrogen bonds involving the NH(+) groups of the [H(6) L](6+) cation, the perchlorate anions and the water molecules. |
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