Diphenyl (isopropyl­amido)­phosphate

The P atom in the title compound, C(15)H(18)NO(3)P, is in a distorted tetra­hedral P(O)(O)(2)N environment; the bond angles at P are in the range 98.16 (6)–115.82 (6)°. In the crystal, adjacent mol­ecules are linked via N—H⋯O=P hydrogen bonds into a chain running parallel to the b axis. The methyl g...

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Detalles Bibliográficos
Autores principales: Sabbaghi, Fahimeh, Pourayoubi, Mehrdad, Nečas, Marek, Babiak, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589035/
https://www.ncbi.nlm.nih.gov/pubmed/23476271
http://dx.doi.org/10.1107/S1600536812047940
Descripción
Sumario:The P atom in the title compound, C(15)H(18)NO(3)P, is in a distorted tetra­hedral P(O)(O)(2)N environment; the bond angles at P are in the range 98.16 (6)–115.82 (6)°. In the crystal, adjacent mol­ecules are linked via N—H⋯O=P hydrogen bonds into a chain running parallel to the b axis. The methyl groups are disordered over two sets of sites in a 0.677 (14):0.323 (14) ratio. The crystal studied was a non-merohedral twin with a refined minor component of 22.31 (4)%.

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