Diphenyl (isopropyl­amido)­phosphate

The P atom in the title compound, C(15)H(18)NO(3)P, is in a distorted tetra­hedral P(O)(O)(2)N environment; the bond angles at P are in the range 98.16 (6)–115.82 (6)°. In the crystal, adjacent mol­ecules are linked via N—H⋯O=P hydrogen bonds into a chain running parallel to the b axis. The methyl g...

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Autores principales: Sabbaghi, Fahimeh, Pourayoubi, Mehrdad, Nečas, Marek, Babiak, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589035/
https://www.ncbi.nlm.nih.gov/pubmed/23476271
http://dx.doi.org/10.1107/S1600536812047940
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author Sabbaghi, Fahimeh
Pourayoubi, Mehrdad
Nečas, Marek
Babiak, Michal
author_facet Sabbaghi, Fahimeh
Pourayoubi, Mehrdad
Nečas, Marek
Babiak, Michal
author_sort Sabbaghi, Fahimeh
collection PubMed
description The P atom in the title compound, C(15)H(18)NO(3)P, is in a distorted tetra­hedral P(O)(O)(2)N environment; the bond angles at P are in the range 98.16 (6)–115.82 (6)°. In the crystal, adjacent mol­ecules are linked via N—H⋯O=P hydrogen bonds into a chain running parallel to the b axis. The methyl groups are disordered over two sets of sites in a 0.677 (14):0.323 (14) ratio. The crystal studied was a non-merohedral twin with a refined minor component of 22.31 (4)%.
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spelling pubmed-35890352013-03-08 Diphenyl (isopropyl­amido)­phosphate Sabbaghi, Fahimeh Pourayoubi, Mehrdad Nečas, Marek Babiak, Michal Acta Crystallogr Sect E Struct Rep Online Organic Papers The P atom in the title compound, C(15)H(18)NO(3)P, is in a distorted tetra­hedral P(O)(O)(2)N environment; the bond angles at P are in the range 98.16 (6)–115.82 (6)°. In the crystal, adjacent mol­ecules are linked via N—H⋯O=P hydrogen bonds into a chain running parallel to the b axis. The methyl groups are disordered over two sets of sites in a 0.677 (14):0.323 (14) ratio. The crystal studied was a non-merohedral twin with a refined minor component of 22.31 (4)%. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3589035/ /pubmed/23476271 http://dx.doi.org/10.1107/S1600536812047940 Text en © Sabbaghi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sabbaghi, Fahimeh
Pourayoubi, Mehrdad
Nečas, Marek
Babiak, Michal
Diphenyl (isopropyl­amido)­phosphate
title Diphenyl (isopropyl­amido)­phosphate
title_full Diphenyl (isopropyl­amido)­phosphate
title_fullStr Diphenyl (isopropyl­amido)­phosphate
title_full_unstemmed Diphenyl (isopropyl­amido)­phosphate
title_short Diphenyl (isopropyl­amido)­phosphate
title_sort diphenyl (isopropyl­amido)­phosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589035/
https://www.ncbi.nlm.nih.gov/pubmed/23476271
http://dx.doi.org/10.1107/S1600536812047940
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AT pourayoubimehrdad diphenylisopropylamidophosphate
AT necasmarek diphenylisopropylamidophosphate
AT babiakmichal diphenylisopropylamidophosphate

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