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5-(Trifluoromethoxy)isatin
The title compound [systematic name: 5-(trifluoromethoxy)-1H-indole-2,3-dione], C(9)H(4)F(3)NO(3), crystallized with two molecules in the asymmetric unit. Intermolecular N—H⋯O hydrogen bonds link the molecules to form layers parallel to the ab plane. In addition, π–π stacking interactions are...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589045/ https://www.ncbi.nlm.nih.gov/pubmed/23476281 http://dx.doi.org/10.1107/S1600536812044297 |
| _version_ | 1782261684921958400 |
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| author | Schutte, M. Pretorius, C. Visser, H.G. Roodt, A. |
| author_facet | Schutte, M. Pretorius, C. Visser, H.G. Roodt, A. |
| author_sort | Schutte, M. |
| collection | PubMed |
| description | The title compound [systematic name: 5-(trifluoromethoxy)-1H-indole-2,3-dione], C(9)H(4)F(3)NO(3), crystallized with two molecules in the asymmetric unit. Intermolecular N—H⋯O hydrogen bonds link the molecules to form layers parallel to the ab plane. In addition, π–π stacking interactions are observed with a centroid–centroid distance of 3.721 (1) Å. The near planarity of the two isatin ring systems is illustrated by by the maximum deviations of 0.023 (1) and 0.025 (1) Å for the N atom in each case. |
| format | Online Article Text |
| id | pubmed-3589045 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35890452013-03-08 5-(Trifluoromethoxy)isatin Schutte, M. Pretorius, C. Visser, H.G. Roodt, A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound [systematic name: 5-(trifluoromethoxy)-1H-indole-2,3-dione], C(9)H(4)F(3)NO(3), crystallized with two molecules in the asymmetric unit. Intermolecular N—H⋯O hydrogen bonds link the molecules to form layers parallel to the ab plane. In addition, π–π stacking interactions are observed with a centroid–centroid distance of 3.721 (1) Å. The near planarity of the two isatin ring systems is illustrated by by the maximum deviations of 0.023 (1) and 0.025 (1) Å for the N atom in each case. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3589045/ /pubmed/23476281 http://dx.doi.org/10.1107/S1600536812044297 Text en © Schutte et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Schutte, M. Pretorius, C. Visser, H.G. Roodt, A. 5-(Trifluoromethoxy)isatin |
| title | 5-(Trifluoromethoxy)isatin |
| title_full | 5-(Trifluoromethoxy)isatin |
| title_fullStr | 5-(Trifluoromethoxy)isatin |
| title_full_unstemmed | 5-(Trifluoromethoxy)isatin |
| title_short | 5-(Trifluoromethoxy)isatin |
| title_sort | 5-(trifluoromethoxy)isatin |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589045/ https://www.ncbi.nlm.nih.gov/pubmed/23476281 http://dx.doi.org/10.1107/S1600536812044297 |
| work_keys_str_mv | AT schuttem 5trifluoromethoxyisatin AT pretoriusc 5trifluoromethoxyisatin AT visserhg 5trifluoromethoxyisatin AT roodta 5trifluoromethoxyisatin |