Tris(naphthalen-1-yl)phosphane chloro­form hemisolvate

The title compound, P(C(10)H(7))(3)·0.5CHCl(3), was isolated after the unsuccessful reaction of KSeCN and tris­(naphthalen-1-yl)phosphane. The solvent mol­ecule is disordered about an inversion center. The effective cone angle of the phosphine is 203°. In the crystal, weak C—H⋯Cl and C—H⋯π inter­act...

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Detalles Bibliográficos
Autores principales: Davis, Wade L., Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589056/
https://www.ncbi.nlm.nih.gov/pubmed/23476292
http://dx.doi.org/10.1107/S1600536812048234
Descripción
Sumario:The title compound, P(C(10)H(7))(3)·0.5CHCl(3), was isolated after the unsuccessful reaction of KSeCN and tris­(naphthalen-1-yl)phosphane. The solvent mol­ecule is disordered about an inversion center. The effective cone angle of the phosphine is 203°. In the crystal, weak C—H⋯Cl and C—H⋯π inter­actions are observed.

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