Tris(naphthalen-1-yl)phosphane chloro­form hemisolvate

The title compound, P(C(10)H(7))(3)·0.5CHCl(3), was isolated after the unsuccessful reaction of KSeCN and tris­(naphthalen-1-yl)phosphane. The solvent mol­ecule is disordered about an inversion center. The effective cone angle of the phosphine is 203°. In the crystal, weak C—H⋯Cl and C—H⋯π inter­act...

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Detalles Bibliográficos
Autores principales: Davis, Wade L., Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589056/
https://www.ncbi.nlm.nih.gov/pubmed/23476292
http://dx.doi.org/10.1107/S1600536812048234
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author Davis, Wade L.
Muller, Alfred
author_facet Davis, Wade L.
Muller, Alfred
author_sort Davis, Wade L.
collection PubMed
description The title compound, P(C(10)H(7))(3)·0.5CHCl(3), was isolated after the unsuccessful reaction of KSeCN and tris­(naphthalen-1-yl)phosphane. The solvent mol­ecule is disordered about an inversion center. The effective cone angle of the phosphine is 203°. In the crystal, weak C—H⋯Cl and C—H⋯π inter­actions are observed.
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spelling pubmed-35890562013-03-08 Tris(naphthalen-1-yl)phosphane chloro­form hemisolvate Davis, Wade L. Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, P(C(10)H(7))(3)·0.5CHCl(3), was isolated after the unsuccessful reaction of KSeCN and tris­(naphthalen-1-yl)phosphane. The solvent mol­ecule is disordered about an inversion center. The effective cone angle of the phosphine is 203°. In the crystal, weak C—H⋯Cl and C—H⋯π inter­actions are observed. International Union of Crystallography 2012-11-30 /pmc/articles/PMC3589056/ /pubmed/23476292 http://dx.doi.org/10.1107/S1600536812048234 Text en © Davis and Muller 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Davis, Wade L.
Muller, Alfred
Tris(naphthalen-1-yl)phosphane chloro­form hemisolvate
title Tris(naphthalen-1-yl)phosphane chloro­form hemisolvate
title_full Tris(naphthalen-1-yl)phosphane chloro­form hemisolvate
title_fullStr Tris(naphthalen-1-yl)phosphane chloro­form hemisolvate
title_full_unstemmed Tris(naphthalen-1-yl)phosphane chloro­form hemisolvate
title_short Tris(naphthalen-1-yl)phosphane chloro­form hemisolvate
title_sort tris(naphthalen-1-yl)phosphane chloro­form hemisolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589056/
https://www.ncbi.nlm.nih.gov/pubmed/23476292
http://dx.doi.org/10.1107/S1600536812048234
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AT mulleralfred trisnaphthalen1ylphosphanechloroformhemisolvate

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