(E)-4-(2-Chloro-1-hy­droxy-2,6,6-tri­methyl­cyclo­hex­yl)but-3-en-2-one

In the title mol­ecule, C(13)H(21)ClO(2), there is an intra­molecular C—H⋯Cl hydrogen bond. The conformation about the C=C bond is E and the six-membered ring has a chair conformation. In the crystal, mol­ecules are linked by pairs of O—H⋯O hydrogen bonds, forming inversion dimers, which are consoli...

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Detalles Bibliográficos
Autores principales: Liu, Shan, Yang, Xiao-Yan, Zhang, Yu-Ling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589057/
https://www.ncbi.nlm.nih.gov/pubmed/23476293
http://dx.doi.org/10.1107/S1600536812048544
Descripción
Sumario:In the title mol­ecule, C(13)H(21)ClO(2), there is an intra­molecular C—H⋯Cl hydrogen bond. The conformation about the C=C bond is E and the six-membered ring has a chair conformation. In the crystal, mol­ecules are linked by pairs of O—H⋯O hydrogen bonds, forming inversion dimers, which are consolidated by C—H⋯O hydrogen bonds. The dimers are linked via C—H.·O hydrogen bonds, forming chains along [100].

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