Methyl 6-oxo-4-phenyl-2-[(Z)-2-(pyridin-2-yl)ethen­yl]-1,4,5,6-tetra­hydro­pyridine-3-carboxyl­ate

In the title mol­ecule, C(20)H(18)N(2)O(3), an intra­molecular N—H⋯O hydrogen bond leads to a cis conformation of the pyridinyl-vinyl fragment. The phenyl and pyridine rings are inclined to one another by 77.3 (1) °. In the crystal, mol­ecules are linked via pairs of C—H⋯O hydrogen bonds, forming in...

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Detalles Bibliográficos
Autores principales: Smits, Rufus, Belyakov, Sergey, Vigante, Brigita, Duburs, Gunars
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589061/
https://www.ncbi.nlm.nih.gov/pubmed/23476297
http://dx.doi.org/10.1107/S1600536812048532
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author Smits, Rufus
Belyakov, Sergey
Vigante, Brigita
Duburs, Gunars
author_facet Smits, Rufus
Belyakov, Sergey
Vigante, Brigita
Duburs, Gunars
author_sort Smits, Rufus
collection PubMed
description In the title mol­ecule, C(20)H(18)N(2)O(3), an intra­molecular N—H⋯O hydrogen bond leads to a cis conformation of the pyridinyl-vinyl fragment. The phenyl and pyridine rings are inclined to one another by 77.3 (1) °. In the crystal, mol­ecules are linked via pairs of C—H⋯O hydrogen bonds, forming inversion dimers. The dimers are linked by C—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming a three-dimensional structure.
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spelling pubmed-35890612013-03-08 Methyl 6-oxo-4-phenyl-2-[(Z)-2-(pyridin-2-yl)ethen­yl]-1,4,5,6-tetra­hydro­pyridine-3-carboxyl­ate Smits, Rufus Belyakov, Sergey Vigante, Brigita Duburs, Gunars Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(20)H(18)N(2)O(3), an intra­molecular N—H⋯O hydrogen bond leads to a cis conformation of the pyridinyl-vinyl fragment. The phenyl and pyridine rings are inclined to one another by 77.3 (1) °. In the crystal, mol­ecules are linked via pairs of C—H⋯O hydrogen bonds, forming inversion dimers. The dimers are linked by C—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming a three-dimensional structure. International Union of Crystallography 2012-11-30 /pmc/articles/PMC3589061/ /pubmed/23476297 http://dx.doi.org/10.1107/S1600536812048532 Text en © Smits et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Smits, Rufus
Belyakov, Sergey
Vigante, Brigita
Duburs, Gunars
Methyl 6-oxo-4-phenyl-2-[(Z)-2-(pyridin-2-yl)ethen­yl]-1,4,5,6-tetra­hydro­pyridine-3-carboxyl­ate
title Methyl 6-oxo-4-phenyl-2-[(Z)-2-(pyridin-2-yl)ethen­yl]-1,4,5,6-tetra­hydro­pyridine-3-carboxyl­ate
title_full Methyl 6-oxo-4-phenyl-2-[(Z)-2-(pyridin-2-yl)ethen­yl]-1,4,5,6-tetra­hydro­pyridine-3-carboxyl­ate
title_fullStr Methyl 6-oxo-4-phenyl-2-[(Z)-2-(pyridin-2-yl)ethen­yl]-1,4,5,6-tetra­hydro­pyridine-3-carboxyl­ate
title_full_unstemmed Methyl 6-oxo-4-phenyl-2-[(Z)-2-(pyridin-2-yl)ethen­yl]-1,4,5,6-tetra­hydro­pyridine-3-carboxyl­ate
title_short Methyl 6-oxo-4-phenyl-2-[(Z)-2-(pyridin-2-yl)ethen­yl]-1,4,5,6-tetra­hydro­pyridine-3-carboxyl­ate
title_sort methyl 6-oxo-4-phenyl-2-[(z)-2-(pyridin-2-yl)ethen­yl]-1,4,5,6-tetra­hydro­pyridine-3-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589061/
https://www.ncbi.nlm.nih.gov/pubmed/23476297
http://dx.doi.org/10.1107/S1600536812048532
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AT vigantebrigita methyl6oxo4phenyl2z2pyridin2ylethenyl1456tetrahydropyridine3carboxylate
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