N,N-Bis(diphenyl­thio­phosphino­yl)-4-ethyl­aniline

The title compound, C(32)H(29)NP(2)S(2), has two mol­ecules in the asymmetric unit, with an r.m.s. difference of 0.218 Å in their best-fit overlay. Both mol­ecules have a slightly distorted trigonal–planar N atom, bonded to two P(V) atoms and a C atom of the 4-ethyl­phenyl unit. The P—N—P angles of...

Descripción completa

Detalles Bibliográficos
Autores principales: Ajibade, Peter A., Onwudiwe, Damian C., Omondi, Bernard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589063/
https://www.ncbi.nlm.nih.gov/pubmed/23476299
http://dx.doi.org/10.1107/S1600536812048416
Descripción
Sumario:The title compound, C(32)H(29)NP(2)S(2), has two mol­ecules in the asymmetric unit, with an r.m.s. difference of 0.218 Å in their best-fit overlay. Both mol­ecules have a slightly distorted trigonal–planar N atom, bonded to two P(V) atoms and a C atom of the 4-ethyl­phenyl unit. The P—N—P angles of 126.34 (11) and 125.98 (11)° are larger than the four C—N—P bond angles. The two S atoms are trans to one another with respect to the P—N—P angle. The crystal structure features C—H⋯π inter­actions. The methyl group in one of the mol­ecules is disordered over two sets of sites, with occupancies of 0.518 (6) and 0.482 (6).

Ejemplares similares