N,N-Bis(diphenyl­thio­phosphino­yl)-4-ethyl­aniline

The title compound, C(32)H(29)NP(2)S(2), has two mol­ecules in the asymmetric unit, with an r.m.s. difference of 0.218 Å in their best-fit overlay. Both mol­ecules have a slightly distorted trigonal–planar N atom, bonded to two P(V) atoms and a C atom of the 4-ethyl­phenyl unit. The P—N—P angles of...

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Detalles Bibliográficos
Autores principales: Ajibade, Peter A., Onwudiwe, Damian C., Omondi, Bernard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589063/
https://www.ncbi.nlm.nih.gov/pubmed/23476299
http://dx.doi.org/10.1107/S1600536812048416
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author Ajibade, Peter A.
Onwudiwe, Damian C.
Omondi, Bernard
author_facet Ajibade, Peter A.
Onwudiwe, Damian C.
Omondi, Bernard
author_sort Ajibade, Peter A.
collection PubMed
description The title compound, C(32)H(29)NP(2)S(2), has two mol­ecules in the asymmetric unit, with an r.m.s. difference of 0.218 Å in their best-fit overlay. Both mol­ecules have a slightly distorted trigonal–planar N atom, bonded to two P(V) atoms and a C atom of the 4-ethyl­phenyl unit. The P—N—P angles of 126.34 (11) and 125.98 (11)° are larger than the four C—N—P bond angles. The two S atoms are trans to one another with respect to the P—N—P angle. The crystal structure features C—H⋯π inter­actions. The methyl group in one of the mol­ecules is disordered over two sets of sites, with occupancies of 0.518 (6) and 0.482 (6).
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spelling pubmed-35890632013-03-08 N,N-Bis(diphenyl­thio­phosphino­yl)-4-ethyl­aniline Ajibade, Peter A. Onwudiwe, Damian C. Omondi, Bernard Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(32)H(29)NP(2)S(2), has two mol­ecules in the asymmetric unit, with an r.m.s. difference of 0.218 Å in their best-fit overlay. Both mol­ecules have a slightly distorted trigonal–planar N atom, bonded to two P(V) atoms and a C atom of the 4-ethyl­phenyl unit. The P—N—P angles of 126.34 (11) and 125.98 (11)° are larger than the four C—N—P bond angles. The two S atoms are trans to one another with respect to the P—N—P angle. The crystal structure features C—H⋯π inter­actions. The methyl group in one of the mol­ecules is disordered over two sets of sites, with occupancies of 0.518 (6) and 0.482 (6). International Union of Crystallography 2012-11-30 /pmc/articles/PMC3589063/ /pubmed/23476299 http://dx.doi.org/10.1107/S1600536812048416 Text en © Ajibade et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ajibade, Peter A.
Onwudiwe, Damian C.
Omondi, Bernard
N,N-Bis(diphenyl­thio­phosphino­yl)-4-ethyl­aniline
title N,N-Bis(diphenyl­thio­phosphino­yl)-4-ethyl­aniline
title_full N,N-Bis(diphenyl­thio­phosphino­yl)-4-ethyl­aniline
title_fullStr N,N-Bis(diphenyl­thio­phosphino­yl)-4-ethyl­aniline
title_full_unstemmed N,N-Bis(diphenyl­thio­phosphino­yl)-4-ethyl­aniline
title_short N,N-Bis(diphenyl­thio­phosphino­yl)-4-ethyl­aniline
title_sort n,n-bis(diphenyl­thio­phosphino­yl)-4-ethyl­aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589063/
https://www.ncbi.nlm.nih.gov/pubmed/23476299
http://dx.doi.org/10.1107/S1600536812048416
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