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3-Hy­droxy-2-meth­oxy­benzamide

The crystal structure of the title compound, C(8)H(9)NO(3), features centrosymmetric dimers with two amide groups inter­connected by a pair of almost linear N—H⋯O hydrogen bonds. Through inter­molecular O—H⋯O inter­actions between phenolic hy­droxy groups and carbonyl O atoms, these dimers are assem...

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Detalles Bibliográficos
Autores principales: Wilbrand, Sabine, Neis, Christian, Hegetschweiler, Kaspar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3589065/
https://www.ncbi.nlm.nih.gov/pubmed/23476301
http://dx.doi.org/10.1107/S1600536812047769
Descripción
Sumario:The crystal structure of the title compound, C(8)H(9)NO(3), features centrosymmetric dimers with two amide groups inter­connected by a pair of almost linear N—H⋯O hydrogen bonds. Through inter­molecular O—H⋯O inter­actions between phenolic hy­droxy groups and carbonyl O atoms, these dimers are assembled into undulating hydrogen-bonded layers parallel to the [101] plane. Additionally, the anti-H(—N) atom of the primary amide group forms an intra­molecular hydrogen bond to the O atom of the meth­oxy group. The amide group froms a dihedral angle of 12.6 (1)° with the phenyl ring.