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Semiconductor nanoparticle-based hydrogels prepared via self-initiated polymerization under sunlight, even visible light
Since ancient times, people have used photosynthesized wood, bamboo, and cotton as building and clothing materials. The advantages of photo polymerization include the mild and easy process. However, the direct use of available sunlight for the preparation of materials is still a challenge due to its...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3590559/ https://www.ncbi.nlm.nih.gov/pubmed/23466566 http://dx.doi.org/10.1038/srep01399 |
Sumario: | Since ancient times, people have used photosynthesized wood, bamboo, and cotton as building and clothing materials. The advantages of photo polymerization include the mild and easy process. However, the direct use of available sunlight for the preparation of materials is still a challenge due to its rather dilute intensity. Here, we show that semiconductor nanoparticles can be used for initiating monomer polymerization under sunlight and for cross-linking to form nanocomposite hydrogels with the aid of clay nanosheets. Hydrogels are an emerging multifunctional platform because they can be easily prepared using solar energy, retain semiconductor nanoparticle properties after immobilization, exhibit excellent mechanical strength (maximum compressive strength of 4.153 MPa and tensile strength 1.535 MPa) and high elasticity (maximum elongation of 2784%), and enable recyclable photodegradation of pollutants. This work suggests that functional nanoparticles can be immobilized in hydrogels for their collective application after combining their mechanical and physiochemical properties. |
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