Regioselective Enzymatic Carboxylation of Phenols and Hydroxystyrene Derivatives

[Image: see text] The enzymatic carboxylation of phenol and styrene derivatives using (de)carboxylases in carbonate buffer proceeded in a highly regioselective fashion: Benzoic acid (de)carboxylases selectively formed o-hydroxybenzoic acid derivatives, phenolic acid (de)carboxylases selectively acte...

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Detalles Bibliográficos
Autores principales: Wuensch, Christiane, Glueck, Silvia M., Gross, Johannes, Koszelewski, Dominik, Schober, Markus, Faber, Kurt
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2012
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3593611/
https://www.ncbi.nlm.nih.gov/pubmed/22471935
http://dx.doi.org/10.1021/ol300385k
Descripción
Sumario:[Image: see text] The enzymatic carboxylation of phenol and styrene derivatives using (de)carboxylases in carbonate buffer proceeded in a highly regioselective fashion: Benzoic acid (de)carboxylases selectively formed o-hydroxybenzoic acid derivatives, phenolic acid (de)carboxylases selectively acted at the β-carbon atom of styrenes forming (E)-cinnamic acids.

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