Regioselective Enzymatic Carboxylation of Phenols and Hydroxystyrene Derivatives

[Image: see text] The enzymatic carboxylation of phenol and styrene derivatives using (de)carboxylases in carbonate buffer proceeded in a highly regioselective fashion: Benzoic acid (de)carboxylases selectively formed o-hydroxybenzoic acid derivatives, phenolic acid (de)carboxylases selectively acte...

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Autores principales: Wuensch, Christiane, Glueck, Silvia M., Gross, Johannes, Koszelewski, Dominik, Schober, Markus, Faber, Kurt
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2012
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3593611/
https://www.ncbi.nlm.nih.gov/pubmed/22471935
http://dx.doi.org/10.1021/ol300385k
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author Wuensch, Christiane
Glueck, Silvia M.
Gross, Johannes
Koszelewski, Dominik
Schober, Markus
Faber, Kurt
author_facet Wuensch, Christiane
Glueck, Silvia M.
Gross, Johannes
Koszelewski, Dominik
Schober, Markus
Faber, Kurt
author_sort Wuensch, Christiane
collection PubMed
description [Image: see text] The enzymatic carboxylation of phenol and styrene derivatives using (de)carboxylases in carbonate buffer proceeded in a highly regioselective fashion: Benzoic acid (de)carboxylases selectively formed o-hydroxybenzoic acid derivatives, phenolic acid (de)carboxylases selectively acted at the β-carbon atom of styrenes forming (E)-cinnamic acids.
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spelling pubmed-35936112013-03-12 Regioselective Enzymatic Carboxylation of Phenols and Hydroxystyrene Derivatives Wuensch, Christiane Glueck, Silvia M. Gross, Johannes Koszelewski, Dominik Schober, Markus Faber, Kurt Org Lett [Image: see text] The enzymatic carboxylation of phenol and styrene derivatives using (de)carboxylases in carbonate buffer proceeded in a highly regioselective fashion: Benzoic acid (de)carboxylases selectively formed o-hydroxybenzoic acid derivatives, phenolic acid (de)carboxylases selectively acted at the β-carbon atom of styrenes forming (E)-cinnamic acids. American Chemical Society 2012-04-03 2012-04-20 /pmc/articles/PMC3593611/ /pubmed/22471935 http://dx.doi.org/10.1021/ol300385k Text en Copyright © 2012 American Chemical Society
spellingShingle Wuensch, Christiane
Glueck, Silvia M.
Gross, Johannes
Koszelewski, Dominik
Schober, Markus
Faber, Kurt
Regioselective Enzymatic Carboxylation of Phenols and Hydroxystyrene Derivatives
title Regioselective Enzymatic Carboxylation of Phenols and Hydroxystyrene Derivatives
title_full Regioselective Enzymatic Carboxylation of Phenols and Hydroxystyrene Derivatives
title_fullStr Regioselective Enzymatic Carboxylation of Phenols and Hydroxystyrene Derivatives
title_full_unstemmed Regioselective Enzymatic Carboxylation of Phenols and Hydroxystyrene Derivatives
title_short Regioselective Enzymatic Carboxylation of Phenols and Hydroxystyrene Derivatives
title_sort regioselective enzymatic carboxylation of phenols and hydroxystyrene derivatives
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3593611/
https://www.ncbi.nlm.nih.gov/pubmed/22471935
http://dx.doi.org/10.1021/ol300385k
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