Asymmetric Diels–Alder reaction with >C=P– functionality of the 2-phosphaindolizine-η(1)-P-aluminium(O-menthoxy) dichloride complex: experimental and theoretical results

The Diels–Alder reaction of the 2-phosphaindolizine-η(1)-P-aluminium(O-menthoxy) dichloride complex with dimethylbutadiene was investigated experimentally and computationally. The >C=P– functionality of the complex reacts with 2,3-dimethylbutadiene with complete diastereoselectivity to afford [2...

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Detalles Bibliográficos
Autores principales: Jangid, Rajendra K, Sogani, Nidhi, Gupta, Neelima, Bansal, Raj Kumar, von Hopffgarten, Moritz, Frenking, Gernot
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3596042/
https://www.ncbi.nlm.nih.gov/pubmed/23504589
http://dx.doi.org/10.3762/bjoc.9.40

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