New simple synthesis of ring-fused 4-alkyl-4H-3,1-benzothiazine-2-thiones: Direct formation from carbon disulfide and (E)-3-(2-aminoaryl)acrylates or (E)-3-(2-aminoaryl)acrylonitriles

A new simple and efficient method to construct ring-fused 4-alkyl-4H-3,1-benzothiazine-2-thione derivatives has been developed from carbon disulfide and (E)-3-(2-aminoaryl)acrylates or (E)-3-(2-aminoaryl)acrylonitriles under mild conditions, without the need for a metal catalyst. The newly developed...

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Autores principales: Ding, Qiuping, Lin, Yuqing, Ding, Guangni, Liao, Fumin, Sang, Xiaoyan, Peng, Yi-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3596062/
https://www.ncbi.nlm.nih.gov/pubmed/23503715
http://dx.doi.org/10.3762/bjoc.9.49
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author Ding, Qiuping
Lin, Yuqing
Ding, Guangni
Liao, Fumin
Sang, Xiaoyan
Peng, Yi-Yuan
author_facet Ding, Qiuping
Lin, Yuqing
Ding, Guangni
Liao, Fumin
Sang, Xiaoyan
Peng, Yi-Yuan
author_sort Ding, Qiuping
collection PubMed
description A new simple and efficient method to construct ring-fused 4-alkyl-4H-3,1-benzothiazine-2-thione derivatives has been developed from carbon disulfide and (E)-3-(2-aminoaryl)acrylates or (E)-3-(2-aminoaryl)acrylonitriles under mild conditions, without the need for a metal catalyst. The newly developed method tolerates a wide range of substrates in moderate to excellent yields. Moreover, this method is advantageous over previous ones for the easy synthesis of reactants.
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spelling pubmed-35960622013-03-15 New simple synthesis of ring-fused 4-alkyl-4H-3,1-benzothiazine-2-thiones: Direct formation from carbon disulfide and (E)-3-(2-aminoaryl)acrylates or (E)-3-(2-aminoaryl)acrylonitriles Ding, Qiuping Lin, Yuqing Ding, Guangni Liao, Fumin Sang, Xiaoyan Peng, Yi-Yuan Beilstein J Org Chem Full Research Paper A new simple and efficient method to construct ring-fused 4-alkyl-4H-3,1-benzothiazine-2-thione derivatives has been developed from carbon disulfide and (E)-3-(2-aminoaryl)acrylates or (E)-3-(2-aminoaryl)acrylonitriles under mild conditions, without the need for a metal catalyst. The newly developed method tolerates a wide range of substrates in moderate to excellent yields. Moreover, this method is advantageous over previous ones for the easy synthesis of reactants. Beilstein-Institut 2013-03-01 /pmc/articles/PMC3596062/ /pubmed/23503715 http://dx.doi.org/10.3762/bjoc.9.49 Text en Copyright © 2013, Ding et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Ding, Qiuping
Lin, Yuqing
Ding, Guangni
Liao, Fumin
Sang, Xiaoyan
Peng, Yi-Yuan
New simple synthesis of ring-fused 4-alkyl-4H-3,1-benzothiazine-2-thiones: Direct formation from carbon disulfide and (E)-3-(2-aminoaryl)acrylates or (E)-3-(2-aminoaryl)acrylonitriles
title New simple synthesis of ring-fused 4-alkyl-4H-3,1-benzothiazine-2-thiones: Direct formation from carbon disulfide and (E)-3-(2-aminoaryl)acrylates or (E)-3-(2-aminoaryl)acrylonitriles
title_full New simple synthesis of ring-fused 4-alkyl-4H-3,1-benzothiazine-2-thiones: Direct formation from carbon disulfide and (E)-3-(2-aminoaryl)acrylates or (E)-3-(2-aminoaryl)acrylonitriles
title_fullStr New simple synthesis of ring-fused 4-alkyl-4H-3,1-benzothiazine-2-thiones: Direct formation from carbon disulfide and (E)-3-(2-aminoaryl)acrylates or (E)-3-(2-aminoaryl)acrylonitriles
title_full_unstemmed New simple synthesis of ring-fused 4-alkyl-4H-3,1-benzothiazine-2-thiones: Direct formation from carbon disulfide and (E)-3-(2-aminoaryl)acrylates or (E)-3-(2-aminoaryl)acrylonitriles
title_short New simple synthesis of ring-fused 4-alkyl-4H-3,1-benzothiazine-2-thiones: Direct formation from carbon disulfide and (E)-3-(2-aminoaryl)acrylates or (E)-3-(2-aminoaryl)acrylonitriles
title_sort new simple synthesis of ring-fused 4-alkyl-4h-3,1-benzothiazine-2-thiones: direct formation from carbon disulfide and (e)-3-(2-aminoaryl)acrylates or (e)-3-(2-aminoaryl)acrylonitriles
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3596062/
https://www.ncbi.nlm.nih.gov/pubmed/23503715
http://dx.doi.org/10.3762/bjoc.9.49
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