Cargando…
Nanoparticles of novel organotin(IV) complexes bearing phosphoric triamide ligands
Four novel organotin(IV) complexes containing phosphoric triamide ligands were synthesized and characterized by multinuclear ((1)H, (31)P, (13)C) NMR, infrared, ultraviolet and fluorescence spectroscopy as well as elemental analysis. The (1)H NMR spectra of complexes 1–4 proved that the Sn atoms ado...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3596101/ https://www.ncbi.nlm.nih.gov/pubmed/23504649 http://dx.doi.org/10.3762/bjnano.4.11 |
_version_ | 1782262465450475520 |
---|---|
author | Shariatinia, Zahra Asadi, Ebadullah Tavasolinasab, Vahid Gholivand, Khodayar |
author_facet | Shariatinia, Zahra Asadi, Ebadullah Tavasolinasab, Vahid Gholivand, Khodayar |
author_sort | Shariatinia, Zahra |
collection | PubMed |
description | Four novel organotin(IV) complexes containing phosphoric triamide ligands were synthesized and characterized by multinuclear ((1)H, (31)P, (13)C) NMR, infrared, ultraviolet and fluorescence spectroscopy as well as elemental analysis. The (1)H NMR spectra of complexes 1–4 proved that the Sn atoms adopt octahedral configurations. The nanoparticles of the complexes were also prepared by ultrasonication, and their SEM micrographs indicated identical spherical morphologies with particles sizes about 20–25 nm. The fluorescence spectra exhibited blue shifts for the maximum wavelength of emission upon complexation. |
format | Online Article Text |
id | pubmed-3596101 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | Beilstein-Institut |
record_format | MEDLINE/PubMed |
spelling | pubmed-35961012013-03-15 Nanoparticles of novel organotin(IV) complexes bearing phosphoric triamide ligands Shariatinia, Zahra Asadi, Ebadullah Tavasolinasab, Vahid Gholivand, Khodayar Beilstein J Nanotechnol Full Research Paper Four novel organotin(IV) complexes containing phosphoric triamide ligands were synthesized and characterized by multinuclear ((1)H, (31)P, (13)C) NMR, infrared, ultraviolet and fluorescence spectroscopy as well as elemental analysis. The (1)H NMR spectra of complexes 1–4 proved that the Sn atoms adopt octahedral configurations. The nanoparticles of the complexes were also prepared by ultrasonication, and their SEM micrographs indicated identical spherical morphologies with particles sizes about 20–25 nm. The fluorescence spectra exhibited blue shifts for the maximum wavelength of emission upon complexation. Beilstein-Institut 2013-02-12 /pmc/articles/PMC3596101/ /pubmed/23504649 http://dx.doi.org/10.3762/bjnano.4.11 Text en Copyright © 2013, Shariatinia et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjnano/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Nanotechnology terms and conditions: (https://www.beilstein-journals.org/bjnano/terms) |
spellingShingle | Full Research Paper Shariatinia, Zahra Asadi, Ebadullah Tavasolinasab, Vahid Gholivand, Khodayar Nanoparticles of novel organotin(IV) complexes bearing phosphoric triamide ligands |
title | Nanoparticles of novel organotin(IV) complexes bearing phosphoric triamide ligands |
title_full | Nanoparticles of novel organotin(IV) complexes bearing phosphoric triamide ligands |
title_fullStr | Nanoparticles of novel organotin(IV) complexes bearing phosphoric triamide ligands |
title_full_unstemmed | Nanoparticles of novel organotin(IV) complexes bearing phosphoric triamide ligands |
title_short | Nanoparticles of novel organotin(IV) complexes bearing phosphoric triamide ligands |
title_sort | nanoparticles of novel organotin(iv) complexes bearing phosphoric triamide ligands |
topic | Full Research Paper |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3596101/ https://www.ncbi.nlm.nih.gov/pubmed/23504649 http://dx.doi.org/10.3762/bjnano.4.11 |
work_keys_str_mv | AT shariatiniazahra nanoparticlesofnovelorganotinivcomplexesbearingphosphorictriamideligands AT asadiebadullah nanoparticlesofnovelorganotinivcomplexesbearingphosphorictriamideligands AT tavasolinasabvahid nanoparticlesofnovelorganotinivcomplexesbearingphosphorictriamideligands AT gholivandkhodayar nanoparticlesofnovelorganotinivcomplexesbearingphosphorictriamideligands |