Methyl Radicals in Oxidative Coupling of Methane Directly Confirmed by Synchrotron VUV Photoionization Mass Spectroscopy

Gas-phase methyl radicals have been long proposed as the key intermediate in catalytic oxidative coupling of methane, but the direct experimental evidence still lacks. Here, employing synchrotron VUV photoionization mass spectroscopy, we have directly observed the formation of gas-phase methyl radic...

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Detalles Bibliográficos
Autores principales: Luo, Liangfeng, Tang, Xiaofeng, Wang, Wendong, Wang, Yu, Sun, Shaobo, Qi, Fei, Huang, Weixin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3620655/
https://www.ncbi.nlm.nih.gov/pubmed/23567985
http://dx.doi.org/10.1038/srep01625

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