Cargando…
Rational design of dynamic ammonium salt catalysts towards more flexible and selective function
This review focuses on the development of dynamic ammonium salt catalysis for selective organic transformations conducted in our laboratory since 2002. Several important concepts in designing of catalysts are described with some examples. In particular, the practial synthesis of chiral 1,1′-binaphth...
Autor principal: | |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Japan Academy
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3621567/ https://www.ncbi.nlm.nih.gov/pubmed/19838010 http://dx.doi.org/10.2183/pjab.85.290 |
_version_ | 1782265723701166080 |
---|---|
author | Ishihara, Kazuaki |
author_facet | Ishihara, Kazuaki |
author_sort | Ishihara, Kazuaki |
collection | PubMed |
description | This review focuses on the development of dynamic ammonium salt catalysis for selective organic transformations conducted in our laboratory since 2002. Several important concepts in designing of catalysts are described with some examples. In particular, the practial synthesis of chiral 1,1′-binaphthyl-2,2′-disulfonic acid (BINSA) and its application in chiral ammonium salt catalysis for the enantioselective direct Mannich-type reaction are described. |
format | Online Article Text |
id | pubmed-3621567 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | The Japan Academy |
record_format | MEDLINE/PubMed |
spelling | pubmed-36215672013-05-08 Rational design of dynamic ammonium salt catalysts towards more flexible and selective function Ishihara, Kazuaki Proc Jpn Acad Ser B Phys Biol Sci Review This review focuses on the development of dynamic ammonium salt catalysis for selective organic transformations conducted in our laboratory since 2002. Several important concepts in designing of catalysts are described with some examples. In particular, the practial synthesis of chiral 1,1′-binaphthyl-2,2′-disulfonic acid (BINSA) and its application in chiral ammonium salt catalysis for the enantioselective direct Mannich-type reaction are described. The Japan Academy 2009-10 /pmc/articles/PMC3621567/ /pubmed/19838010 http://dx.doi.org/10.2183/pjab.85.290 Text en © 2009 The Japan Academy This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Review Ishihara, Kazuaki Rational design of dynamic ammonium salt catalysts towards more flexible and selective function |
title | Rational design of dynamic ammonium salt catalysts towards more flexible and selective function |
title_full | Rational design of dynamic ammonium salt catalysts towards more flexible and selective function |
title_fullStr | Rational design of dynamic ammonium salt catalysts towards more flexible and selective function |
title_full_unstemmed | Rational design of dynamic ammonium salt catalysts towards more flexible and selective function |
title_short | Rational design of dynamic ammonium salt catalysts towards more flexible and selective function |
title_sort | rational design of dynamic ammonium salt catalysts towards more flexible and selective function |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3621567/ https://www.ncbi.nlm.nih.gov/pubmed/19838010 http://dx.doi.org/10.2183/pjab.85.290 |
work_keys_str_mv | AT ishiharakazuaki rationaldesignofdynamicammoniumsaltcatalyststowardsmoreflexibleandselectivefunction |