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Rational design of dynamic ammonium salt catalysts towards more flexible and selective function

This review focuses on the development of dynamic ammonium salt catalysis for selective organic transformations conducted in our laboratory since 2002. Several important concepts in designing of catalysts are described with some examples. In particular, the practial synthesis of chiral 1,1′-binaphth...

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Detalles Bibliográficos
Autor principal: Ishihara, Kazuaki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Japan Academy 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3621567/
https://www.ncbi.nlm.nih.gov/pubmed/19838010
http://dx.doi.org/10.2183/pjab.85.290
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author Ishihara, Kazuaki
author_facet Ishihara, Kazuaki
author_sort Ishihara, Kazuaki
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description This review focuses on the development of dynamic ammonium salt catalysis for selective organic transformations conducted in our laboratory since 2002. Several important concepts in designing of catalysts are described with some examples. In particular, the practial synthesis of chiral 1,1′-binaphthyl-2,2′-disulfonic acid (BINSA) and its application in chiral ammonium salt catalysis for the enantioselective direct Mannich-type reaction are described.
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spelling pubmed-36215672013-05-08 Rational design of dynamic ammonium salt catalysts towards more flexible and selective function Ishihara, Kazuaki Proc Jpn Acad Ser B Phys Biol Sci Review This review focuses on the development of dynamic ammonium salt catalysis for selective organic transformations conducted in our laboratory since 2002. Several important concepts in designing of catalysts are described with some examples. In particular, the practial synthesis of chiral 1,1′-binaphthyl-2,2′-disulfonic acid (BINSA) and its application in chiral ammonium salt catalysis for the enantioselective direct Mannich-type reaction are described. The Japan Academy 2009-10 /pmc/articles/PMC3621567/ /pubmed/19838010 http://dx.doi.org/10.2183/pjab.85.290 Text en © 2009 The Japan Academy This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Review
Ishihara, Kazuaki
Rational design of dynamic ammonium salt catalysts towards more flexible and selective function
title Rational design of dynamic ammonium salt catalysts towards more flexible and selective function
title_full Rational design of dynamic ammonium salt catalysts towards more flexible and selective function
title_fullStr Rational design of dynamic ammonium salt catalysts towards more flexible and selective function
title_full_unstemmed Rational design of dynamic ammonium salt catalysts towards more flexible and selective function
title_short Rational design of dynamic ammonium salt catalysts towards more flexible and selective function
title_sort rational design of dynamic ammonium salt catalysts towards more flexible and selective function
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3621567/
https://www.ncbi.nlm.nih.gov/pubmed/19838010
http://dx.doi.org/10.2183/pjab.85.290
work_keys_str_mv AT ishiharakazuaki rationaldesignofdynamicammoniumsaltcatalyststowardsmoreflexibleandselectivefunction