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Kinetics and mechanism of the anilinolysis of aryl phenyl isothiocyanophosphates in acetonitrile
Kinetic studies on the reactions of Y-aryl phenyl isothiocyanophosphates with substituted X-anilines and deuterated X-anilines were carried out in acetonitrile at 55.0 °C. The free-energy relationships with X in the nucleophiles were biphasic concave upwards with a break region between X = H and 4-C...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Beilstein-Institut
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3628914/ https://www.ncbi.nlm.nih.gov/pubmed/23616804 http://dx.doi.org/10.3762/bjoc.9.68 |