Bis[1,2-bis­(eth­oxy­carbon­yl)ethene-1,2-dithiol­ato-κ(2) S,S′]bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)tetra-μ(3)-sulfido-diiron(IV)diiron(III)(3 Fe—Fe)

The title compound, [Fe(4)(C(10)H(15))(2)(C(8)H(10)O(4)S(2))(2)S(4)], contains a twisted Fe(4)S(4) cubane-like core. A twofold rotation axis passes through the Fe(4)S(4) core, completing the coordination of the four Fe atoms with two penta­methyl­cyclo­penta­dienyl ligands and two chelating dithiol­...

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Detalles Bibliográficos
Autores principales: Ito, Shohei, Hisamichi, Nozomu, Takase, Tsugiko, Inomata, Shinji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629468/
https://www.ncbi.nlm.nih.gov/pubmed/23633986
http://dx.doi.org/10.1107/S1600536813005564
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author Ito, Shohei
Hisamichi, Nozomu
Takase, Tsugiko
Inomata, Shinji
author_facet Ito, Shohei
Hisamichi, Nozomu
Takase, Tsugiko
Inomata, Shinji
author_sort Ito, Shohei
collection PubMed
description The title compound, [Fe(4)(C(10)H(15))(2)(C(8)H(10)O(4)S(2))(2)S(4)], contains a twisted Fe(4)S(4) cubane-like core. A twofold rotation axis passes through the Fe(4)S(4) core, completing the coordination of the four Fe atoms with two penta­methyl­cyclo­penta­dienyl ligands and two chelating dithiol­ate ligands. There are three short Fe—Fe and three long Fe⋯Fe contacts in the Fe(4)S(4) core, suggesting bonding and non-bonding inter­actions, respectively. The Fe—S bonds in the Fe(4)S(4) core range from 2.1523 (5) to 2.2667 (6) Å and are somewhat longer than the Fe—S bonds involving the dithiol­ate ligand.
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spelling pubmed-36294682013-04-30 Bis[1,2-bis­(eth­oxy­carbon­yl)ethene-1,2-dithiol­ato-κ(2) S,S′]bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)tetra-μ(3)-sulfido-diiron(IV)diiron(III)(3 Fe—Fe) Ito, Shohei Hisamichi, Nozomu Takase, Tsugiko Inomata, Shinji Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(4)(C(10)H(15))(2)(C(8)H(10)O(4)S(2))(2)S(4)], contains a twisted Fe(4)S(4) cubane-like core. A twofold rotation axis passes through the Fe(4)S(4) core, completing the coordination of the four Fe atoms with two penta­methyl­cyclo­penta­dienyl ligands and two chelating dithiol­ate ligands. There are three short Fe—Fe and three long Fe⋯Fe contacts in the Fe(4)S(4) core, suggesting bonding and non-bonding inter­actions, respectively. The Fe—S bonds in the Fe(4)S(4) core range from 2.1523 (5) to 2.2667 (6) Å and are somewhat longer than the Fe—S bonds involving the dithiol­ate ligand. International Union of Crystallography 2013-03-02 /pmc/articles/PMC3629468/ /pubmed/23633986 http://dx.doi.org/10.1107/S1600536813005564 Text en © Ito et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ito, Shohei
Hisamichi, Nozomu
Takase, Tsugiko
Inomata, Shinji
Bis[1,2-bis­(eth­oxy­carbon­yl)ethene-1,2-dithiol­ato-κ(2) S,S′]bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)tetra-μ(3)-sulfido-diiron(IV)diiron(III)(3 Fe—Fe)
title Bis[1,2-bis­(eth­oxy­carbon­yl)ethene-1,2-dithiol­ato-κ(2) S,S′]bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)tetra-μ(3)-sulfido-diiron(IV)diiron(III)(3 Fe—Fe)
title_full Bis[1,2-bis­(eth­oxy­carbon­yl)ethene-1,2-dithiol­ato-κ(2) S,S′]bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)tetra-μ(3)-sulfido-diiron(IV)diiron(III)(3 Fe—Fe)
title_fullStr Bis[1,2-bis­(eth­oxy­carbon­yl)ethene-1,2-dithiol­ato-κ(2) S,S′]bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)tetra-μ(3)-sulfido-diiron(IV)diiron(III)(3 Fe—Fe)
title_full_unstemmed Bis[1,2-bis­(eth­oxy­carbon­yl)ethene-1,2-dithiol­ato-κ(2) S,S′]bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)tetra-μ(3)-sulfido-diiron(IV)diiron(III)(3 Fe—Fe)
title_short Bis[1,2-bis­(eth­oxy­carbon­yl)ethene-1,2-dithiol­ato-κ(2) S,S′]bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)tetra-μ(3)-sulfido-diiron(IV)diiron(III)(3 Fe—Fe)
title_sort bis[1,2-bis­(eth­oxy­carbon­yl)ethene-1,2-dithiol­ato-κ(2) s,s′]bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)tetra-μ(3)-sulfido-diiron(iv)diiron(iii)(3 fe—fe)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629468/
https://www.ncbi.nlm.nih.gov/pubmed/23633986
http://dx.doi.org/10.1107/S1600536813005564
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