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[(2R,3S)-Butane-1,2,3,4-tetraol-κ(3) O (1),O (2),O (3)](ethanol-κO)tris(nitrato-κ(2) O,O′)samarium(III)
The title Sm(III)–erythritol complex, [Sm(NO(3))(3)(C(2)H(6)O)(C(4)H(10)O(4))], is isotypic with its Nd, Eu, Y, Gd, Tb and Ho analogues. The Sm(III) cation exhibits a coordination number of ten and is chelated by a tridentate erythritol ligand and three bidentate nitrate anions. It is additionally c...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629469/ https://www.ncbi.nlm.nih.gov/pubmed/23633987 http://dx.doi.org/10.1107/S1600536813003255 |
| _version_ | 1782266585290899456 |
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| author | Xue, Jun-Hui Hua, Xiao-Hui Yang, Li-Min Xu, Yi-Zhuang Wu, Jin-Guang |
| author_facet | Xue, Jun-Hui Hua, Xiao-Hui Yang, Li-Min Xu, Yi-Zhuang Wu, Jin-Guang |
| author_sort | Xue, Jun-Hui |
| collection | PubMed |
| description | The title Sm(III)–erythritol complex, [Sm(NO(3))(3)(C(2)H(6)O)(C(4)H(10)O(4))], is isotypic with its Nd, Eu, Y, Gd, Tb and Ho analogues. The Sm(III) cation exhibits a coordination number of ten and is chelated by a tridentate erythritol ligand and three bidentate nitrate anions. It is additionally coordinated by an O atom of an ethanol molecule, completing an irregular coordination sphere. The Sm—O bond lengths range from 2.416 (2) to 2.611 (2) Å. In the crystal, extensive O—H⋯O hydrogen bonding involving all hydroxy groups and some of the nitrate O atoms links the molecules into a three-dimensional network. |
| format | Online Article Text |
| id | pubmed-3629469 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-36294692013-04-30 [(2R,3S)-Butane-1,2,3,4-tetraol-κ(3) O (1),O (2),O (3)](ethanol-κO)tris(nitrato-κ(2) O,O′)samarium(III) Xue, Jun-Hui Hua, Xiao-Hui Yang, Li-Min Xu, Yi-Zhuang Wu, Jin-Guang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Sm(III)–erythritol complex, [Sm(NO(3))(3)(C(2)H(6)O)(C(4)H(10)O(4))], is isotypic with its Nd, Eu, Y, Gd, Tb and Ho analogues. The Sm(III) cation exhibits a coordination number of ten and is chelated by a tridentate erythritol ligand and three bidentate nitrate anions. It is additionally coordinated by an O atom of an ethanol molecule, completing an irregular coordination sphere. The Sm—O bond lengths range from 2.416 (2) to 2.611 (2) Å. In the crystal, extensive O—H⋯O hydrogen bonding involving all hydroxy groups and some of the nitrate O atoms links the molecules into a three-dimensional network. International Union of Crystallography 2013-03-02 /pmc/articles/PMC3629469/ /pubmed/23633987 http://dx.doi.org/10.1107/S1600536813003255 Text en © Xue et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xue, Jun-Hui Hua, Xiao-Hui Yang, Li-Min Xu, Yi-Zhuang Wu, Jin-Guang [(2R,3S)-Butane-1,2,3,4-tetraol-κ(3) O (1),O (2),O (3)](ethanol-κO)tris(nitrato-κ(2) O,O′)samarium(III) |
| title | [(2R,3S)-Butane-1,2,3,4-tetraol-κ(3)
O
(1),O
(2),O
(3)](ethanol-κO)tris(nitrato-κ(2)
O,O′)samarium(III) |
| title_full | [(2R,3S)-Butane-1,2,3,4-tetraol-κ(3)
O
(1),O
(2),O
(3)](ethanol-κO)tris(nitrato-κ(2)
O,O′)samarium(III) |
| title_fullStr | [(2R,3S)-Butane-1,2,3,4-tetraol-κ(3)
O
(1),O
(2),O
(3)](ethanol-κO)tris(nitrato-κ(2)
O,O′)samarium(III) |
| title_full_unstemmed | [(2R,3S)-Butane-1,2,3,4-tetraol-κ(3)
O
(1),O
(2),O
(3)](ethanol-κO)tris(nitrato-κ(2)
O,O′)samarium(III) |
| title_short | [(2R,3S)-Butane-1,2,3,4-tetraol-κ(3)
O
(1),O
(2),O
(3)](ethanol-κO)tris(nitrato-κ(2)
O,O′)samarium(III) |
| title_sort | [(2r,3s)-butane-1,2,3,4-tetraol-κ(3)
o
(1),o
(2),o
(3)](ethanol-κo)tris(nitrato-κ(2)
o,o′)samarium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629469/ https://www.ncbi.nlm.nih.gov/pubmed/23633987 http://dx.doi.org/10.1107/S1600536813003255 |
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