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Bis{1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole-κN (3)}bis(3,5-dicarboxybenzoato-κ(2) O (1),O (1′))nickel(II) octahydrate
In the title complex, [Ni(C(9)H(5)O(6))(2)(C(11)H(10)N(4))(2)]·8H(2)O, the Ni(II) ion exhibits site symmetry 2. It has a distorted octahedral coordination defined by two N atoms from two symmetry-related 1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole ligands and four O atoms from two symmetry-relat...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629470/ https://www.ncbi.nlm.nih.gov/pubmed/23633988 http://dx.doi.org/10.1107/S1600536813003322 |
| _version_ | 1782266585516343296 |
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| author | Jia, Yong-Yan Fan, Jing-Jing Yin, Xiang-Ge Zhao, Wen-Long |
| author_facet | Jia, Yong-Yan Fan, Jing-Jing Yin, Xiang-Ge Zhao, Wen-Long |
| author_sort | Jia, Yong-Yan |
| collection | PubMed |
| description | In the title complex, [Ni(C(9)H(5)O(6))(2)(C(11)H(10)N(4))(2)]·8H(2)O, the Ni(II) ion exhibits site symmetry 2. It has a distorted octahedral coordination defined by two N atoms from two symmetry-related 1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole ligands and four O atoms from two symmetry-related 3,5-dicarboxybenzoate anions. In the crystal, the complex molecules and solvent water molecules are linked via O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, forming a three-dimensional structure. There are also a number of C—H⋯O interactions present. |
| format | Online Article Text |
| id | pubmed-3629470 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-36294702013-04-30 Bis{1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole-κN (3)}bis(3,5-dicarboxybenzoato-κ(2) O (1),O (1′))nickel(II) octahydrate Jia, Yong-Yan Fan, Jing-Jing Yin, Xiang-Ge Zhao, Wen-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(9)H(5)O(6))(2)(C(11)H(10)N(4))(2)]·8H(2)O, the Ni(II) ion exhibits site symmetry 2. It has a distorted octahedral coordination defined by two N atoms from two symmetry-related 1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole ligands and four O atoms from two symmetry-related 3,5-dicarboxybenzoate anions. In the crystal, the complex molecules and solvent water molecules are linked via O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, forming a three-dimensional structure. There are also a number of C—H⋯O interactions present. International Union of Crystallography 2013-03-02 /pmc/articles/PMC3629470/ /pubmed/23633988 http://dx.doi.org/10.1107/S1600536813003322 Text en © Jia et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Jia, Yong-Yan Fan, Jing-Jing Yin, Xiang-Ge Zhao, Wen-Long Bis{1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole-κN (3)}bis(3,5-dicarboxybenzoato-κ(2) O (1),O (1′))nickel(II) octahydrate |
| title | Bis{1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole-κN
(3)}bis(3,5-dicarboxybenzoato-κ(2)
O
(1),O
(1′))nickel(II) octahydrate |
| title_full | Bis{1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole-κN
(3)}bis(3,5-dicarboxybenzoato-κ(2)
O
(1),O
(1′))nickel(II) octahydrate |
| title_fullStr | Bis{1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole-κN
(3)}bis(3,5-dicarboxybenzoato-κ(2)
O
(1),O
(1′))nickel(II) octahydrate |
| title_full_unstemmed | Bis{1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole-κN
(3)}bis(3,5-dicarboxybenzoato-κ(2)
O
(1),O
(1′))nickel(II) octahydrate |
| title_short | Bis{1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole-κN
(3)}bis(3,5-dicarboxybenzoato-κ(2)
O
(1),O
(1′))nickel(II) octahydrate |
| title_sort | bis{1-[(1h-benzimidazol-1-yl)methyl]-1h-imidazole-κn
(3)}bis(3,5-dicarboxybenzoato-κ(2)
o
(1),o
(1′))nickel(ii) octahydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629470/ https://www.ncbi.nlm.nih.gov/pubmed/23633988 http://dx.doi.org/10.1107/S1600536813003322 |
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