Cargando…
Poly[[(μ(4)-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide]
In the structure of the title compound, {[Na(C(6)H(15)N(3)O(3))]Br}(n), the sodium cation and the bromide anion are both located on threefold rotation axes. The sodium cation is bonded to the three hydroxy groups of one 1,3,5-triamino-1,3,5-trideoxy-cis-inositol (taci) ligand, with the taci ligand...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629471/ https://www.ncbi.nlm.nih.gov/pubmed/23633989 http://dx.doi.org/10.1107/S1600536813005618 |
_version_ | 1782266585737592832 |
---|---|
author | Reiss, Guido J. Hegetschweiler, Kaspar |
author_facet | Reiss, Guido J. Hegetschweiler, Kaspar |
author_sort | Reiss, Guido J. |
collection | PubMed |
description | In the structure of the title compound, {[Na(C(6)H(15)N(3)O(3))]Br}(n), the sodium cation and the bromide anion are both located on threefold rotation axes. The sodium cation is bonded to the three hydroxy groups of one 1,3,5-triamino-1,3,5-trideoxy-cis-inositol (taci) ligand, with the taci ligand residing around the same threefold rotation axis as the sodium ion. The coordination sphere of the sodium ion is completed by three amino groups of three neighbouring taci molecules. Hence, this type of coordination constitutes a three-dimensional open framework with channels along the c axis which are filled with the bromide counter-anions. Each bromide ion forms three symmetry-related hydrogen bonds to both the hydroxy and the amino groups of neighbouring taci ligands. |
format | Online Article Text |
id | pubmed-3629471 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36294712013-04-30 Poly[[(μ(4)-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide] Reiss, Guido J. Hegetschweiler, Kaspar Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, {[Na(C(6)H(15)N(3)O(3))]Br}(n), the sodium cation and the bromide anion are both located on threefold rotation axes. The sodium cation is bonded to the three hydroxy groups of one 1,3,5-triamino-1,3,5-trideoxy-cis-inositol (taci) ligand, with the taci ligand residing around the same threefold rotation axis as the sodium ion. The coordination sphere of the sodium ion is completed by three amino groups of three neighbouring taci molecules. Hence, this type of coordination constitutes a three-dimensional open framework with channels along the c axis which are filled with the bromide counter-anions. Each bromide ion forms three symmetry-related hydrogen bonds to both the hydroxy and the amino groups of neighbouring taci ligands. International Union of Crystallography 2013-03-02 /pmc/articles/PMC3629471/ /pubmed/23633989 http://dx.doi.org/10.1107/S1600536813005618 Text en © Reiss and Hegetschweiler 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Reiss, Guido J. Hegetschweiler, Kaspar Poly[[(μ(4)-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide] |
title | Poly[[(μ(4)-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide] |
title_full | Poly[[(μ(4)-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide] |
title_fullStr | Poly[[(μ(4)-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide] |
title_full_unstemmed | Poly[[(μ(4)-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide] |
title_short | Poly[[(μ(4)-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide] |
title_sort | poly[[(μ(4)-1,3,5-triamino-1,3,5-trideoxy-cis-inositol)sodium] bromide] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629471/ https://www.ncbi.nlm.nih.gov/pubmed/23633989 http://dx.doi.org/10.1107/S1600536813005618 |
work_keys_str_mv | AT reissguidoj polym4135triamino135trideoxycisinositolsodiumbromide AT hegetschweilerkaspar polym4135triamino135trideoxycisinositolsodiumbromide |