4-(Dimethyl­amino)­pyridinium tetra­chloridoferrate(III)

The title salt, (C(7)H(11)N(2))[FeCl(4)], consists of one essentially planar (the r.m.s. deviation for all non-H atoms being 0.004 Å) 4-(dimethyl­amino)­pyridinium cation and a tetra­hedral tetra­chloridoferrate(III) anion. The cations and anions are arranged in layers parallel to (010). Besides ele...

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Detalles Bibliográficos
Autores principales: Khadri, Amina, Bouchene, Rafika, Bouacida, Sofiane, Merazig, Hocine, Roisnel, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629474/
https://www.ncbi.nlm.nih.gov/pubmed/23633992
http://dx.doi.org/10.1107/S160053681300603X
Descripción
Sumario:The title salt, (C(7)H(11)N(2))[FeCl(4)], consists of one essentially planar (the r.m.s. deviation for all non-H atoms being 0.004 Å) 4-(dimethyl­amino)­pyridinium cation and a tetra­hedral tetra­chloridoferrate(III) anion. The cations and anions are arranged in layers parallel to (010). Besides electrostatic inter­actions, the crystal packing features N—H⋯Cl and C—H⋯Cl hydrogen bonds between cations and anions, forming a three-dimensional network.

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