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(2-Amino-7-methyl-4-oxidopteridine-6-carboxylato-κ(3) O (4),N (5),O (6))(ethane-1,2-diamine-κ(2) N,N′)(1H-imidazole-κN (3))nickel(II) dihydrate
In the title complex, [Ni(C(8)H(5)N(5)O(3))(C(2)H(8)N(2))(C(3)N(2)H(4))]·2H(2)O, a tridentate 2-amino-7-methyl-4-oxidopteridine-6-carboxylate (pterin) ligand, a bidentate ancillary ethane-1,2-diamine (en) ligand and a monodentate 1H-imidazole (im) ligand complete a distorted octahedral geometry ar...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629476/ https://www.ncbi.nlm.nih.gov/pubmed/23633994 http://dx.doi.org/10.1107/S1600536813005898 |
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author | Baisya, Siddhartha S. Roy, Parag S. |
author_facet | Baisya, Siddhartha S. Roy, Parag S. |
author_sort | Baisya, Siddhartha S. |
collection | PubMed |
description | In the title complex, [Ni(C(8)H(5)N(5)O(3))(C(2)H(8)N(2))(C(3)N(2)H(4))]·2H(2)O, a tridentate 2-amino-7-methyl-4-oxidopteridine-6-carboxylate (pterin) ligand, a bidentate ancillary ethane-1,2-diamine (en) ligand and a monodentate 1H-imidazole (im) ligand complete a distorted octahedral geometry around the Ni(II) atom. The pterin ligand forms two chelate rings. Both the en and im ligands are arranged nearly orthogonally relative to the pterin ligand [dihedral angles between the mean planes of the en and pterin ligands and of the im and pterin ligands are 84.62 (9) and 85.14 (9)°, respectively]. N—H⋯N, N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds link the complex molecules and lattice water molecules into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3629476 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36294762013-04-30 (2-Amino-7-methyl-4-oxidopteridine-6-carboxylato-κ(3) O (4),N (5),O (6))(ethane-1,2-diamine-κ(2) N,N′)(1H-imidazole-κN (3))nickel(II) dihydrate Baisya, Siddhartha S. Roy, Parag S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(8)H(5)N(5)O(3))(C(2)H(8)N(2))(C(3)N(2)H(4))]·2H(2)O, a tridentate 2-amino-7-methyl-4-oxidopteridine-6-carboxylate (pterin) ligand, a bidentate ancillary ethane-1,2-diamine (en) ligand and a monodentate 1H-imidazole (im) ligand complete a distorted octahedral geometry around the Ni(II) atom. The pterin ligand forms two chelate rings. Both the en and im ligands are arranged nearly orthogonally relative to the pterin ligand [dihedral angles between the mean planes of the en and pterin ligands and of the im and pterin ligands are 84.62 (9) and 85.14 (9)°, respectively]. N—H⋯N, N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds link the complex molecules and lattice water molecules into a three-dimensional network. International Union of Crystallography 2013-03-09 /pmc/articles/PMC3629476/ /pubmed/23633994 http://dx.doi.org/10.1107/S1600536813005898 Text en © Baisya and Roy 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Baisya, Siddhartha S. Roy, Parag S. (2-Amino-7-methyl-4-oxidopteridine-6-carboxylato-κ(3) O (4),N (5),O (6))(ethane-1,2-diamine-κ(2) N,N′)(1H-imidazole-κN (3))nickel(II) dihydrate |
title | (2-Amino-7-methyl-4-oxidopteridine-6-carboxylato-κ(3)
O
(4),N
(5),O
(6))(ethane-1,2-diamine-κ(2)
N,N′)(1H-imidazole-κN
(3))nickel(II) dihydrate |
title_full | (2-Amino-7-methyl-4-oxidopteridine-6-carboxylato-κ(3)
O
(4),N
(5),O
(6))(ethane-1,2-diamine-κ(2)
N,N′)(1H-imidazole-κN
(3))nickel(II) dihydrate |
title_fullStr | (2-Amino-7-methyl-4-oxidopteridine-6-carboxylato-κ(3)
O
(4),N
(5),O
(6))(ethane-1,2-diamine-κ(2)
N,N′)(1H-imidazole-κN
(3))nickel(II) dihydrate |
title_full_unstemmed | (2-Amino-7-methyl-4-oxidopteridine-6-carboxylato-κ(3)
O
(4),N
(5),O
(6))(ethane-1,2-diamine-κ(2)
N,N′)(1H-imidazole-κN
(3))nickel(II) dihydrate |
title_short | (2-Amino-7-methyl-4-oxidopteridine-6-carboxylato-κ(3)
O
(4),N
(5),O
(6))(ethane-1,2-diamine-κ(2)
N,N′)(1H-imidazole-κN
(3))nickel(II) dihydrate |
title_sort | (2-amino-7-methyl-4-oxidopteridine-6-carboxylato-κ(3)
o
(4),n
(5),o
(6))(ethane-1,2-diamine-κ(2)
n,n′)(1h-imidazole-κn
(3))nickel(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629476/ https://www.ncbi.nlm.nih.gov/pubmed/23633994 http://dx.doi.org/10.1107/S1600536813005898 |
work_keys_str_mv | AT baisyasiddharthas 2amino7methyl4oxidopteridine6carboxylatok3o4n5o6ethane12diaminek2nn1himidazolekn3nickeliidihydrate AT royparags 2amino7methyl4oxidopteridine6carboxylatok3o4n5o6ethane12diaminek2nn1himidazolekn3nickeliidihydrate |