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(2-Amino-7-methyl-4-oxidopteridine-6-carboxyl­ato-κ(3) O (4),N (5),O (6))(ethane-1,2-diamine-κ(2) N,N′)(1H-imidazole-κN (3))nickel(II) dihydrate

In the title complex, [Ni(C(8)H(5)N(5)O(3))(C(2)H(8)N(2))(C(3)N(2)H(4))]·2H(2)O, a tridentate 2-amino-7-methyl-4-oxidopteridine-6-carboxyl­ate (pterin) ligand, a bidentate ancillary ethane-1,2-diamine (en) ligand and a monodentate 1H-imidazole (im) ligand complete a distorted octa­hedral geometry ar...

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Detalles Bibliográficos
Autores principales: Baisya, Siddhartha S., Roy, Parag S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629476/
https://www.ncbi.nlm.nih.gov/pubmed/23633994
http://dx.doi.org/10.1107/S1600536813005898
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author Baisya, Siddhartha S.
Roy, Parag S.
author_facet Baisya, Siddhartha S.
Roy, Parag S.
author_sort Baisya, Siddhartha S.
collection PubMed
description In the title complex, [Ni(C(8)H(5)N(5)O(3))(C(2)H(8)N(2))(C(3)N(2)H(4))]·2H(2)O, a tridentate 2-amino-7-methyl-4-oxidopteridine-6-carboxyl­ate (pterin) ligand, a bidentate ancillary ethane-1,2-diamine (en) ligand and a monodentate 1H-imidazole (im) ligand complete a distorted octa­hedral geometry around the Ni(II) atom. The pterin ligand forms two chelate rings. Both the en and im ligands are arranged nearly orthogonally relative to the pterin ligand [dihedral angles between the mean planes of the en and pterin ligands and of the im and pterin ligands are 84.62 (9) and 85.14 (9)°, respectively]. N—H⋯N, N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds link the complex mol­ecules and lattice water mol­ecules into a three-dimensional network.
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spelling pubmed-36294762013-04-30 (2-Amino-7-methyl-4-oxidopteridine-6-carboxyl­ato-κ(3) O (4),N (5),O (6))(ethane-1,2-diamine-κ(2) N,N′)(1H-imidazole-κN (3))nickel(II) dihydrate Baisya, Siddhartha S. Roy, Parag S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(8)H(5)N(5)O(3))(C(2)H(8)N(2))(C(3)N(2)H(4))]·2H(2)O, a tridentate 2-amino-7-methyl-4-oxidopteridine-6-carboxyl­ate (pterin) ligand, a bidentate ancillary ethane-1,2-diamine (en) ligand and a monodentate 1H-imidazole (im) ligand complete a distorted octa­hedral geometry around the Ni(II) atom. The pterin ligand forms two chelate rings. Both the en and im ligands are arranged nearly orthogonally relative to the pterin ligand [dihedral angles between the mean planes of the en and pterin ligands and of the im and pterin ligands are 84.62 (9) and 85.14 (9)°, respectively]. N—H⋯N, N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds link the complex mol­ecules and lattice water mol­ecules into a three-dimensional network. International Union of Crystallography 2013-03-09 /pmc/articles/PMC3629476/ /pubmed/23633994 http://dx.doi.org/10.1107/S1600536813005898 Text en © Baisya and Roy 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Baisya, Siddhartha S.
Roy, Parag S.
(2-Amino-7-methyl-4-oxidopteridine-6-carboxyl­ato-κ(3) O (4),N (5),O (6))(ethane-1,2-diamine-κ(2) N,N′)(1H-imidazole-κN (3))nickel(II) dihydrate
title (2-Amino-7-methyl-4-oxidopteridine-6-carboxyl­ato-κ(3) O (4),N (5),O (6))(ethane-1,2-diamine-κ(2) N,N′)(1H-imidazole-κN (3))nickel(II) dihydrate
title_full (2-Amino-7-methyl-4-oxidopteridine-6-carboxyl­ato-κ(3) O (4),N (5),O (6))(ethane-1,2-diamine-κ(2) N,N′)(1H-imidazole-κN (3))nickel(II) dihydrate
title_fullStr (2-Amino-7-methyl-4-oxidopteridine-6-carboxyl­ato-κ(3) O (4),N (5),O (6))(ethane-1,2-diamine-κ(2) N,N′)(1H-imidazole-κN (3))nickel(II) dihydrate
title_full_unstemmed (2-Amino-7-methyl-4-oxidopteridine-6-carboxyl­ato-κ(3) O (4),N (5),O (6))(ethane-1,2-diamine-κ(2) N,N′)(1H-imidazole-κN (3))nickel(II) dihydrate
title_short (2-Amino-7-methyl-4-oxidopteridine-6-carboxyl­ato-κ(3) O (4),N (5),O (6))(ethane-1,2-diamine-κ(2) N,N′)(1H-imidazole-κN (3))nickel(II) dihydrate
title_sort (2-amino-7-methyl-4-oxidopteridine-6-carboxyl­ato-κ(3) o (4),n (5),o (6))(ethane-1,2-diamine-κ(2) n,n′)(1h-imidazole-κn (3))nickel(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629476/
https://www.ncbi.nlm.nih.gov/pubmed/23633994
http://dx.doi.org/10.1107/S1600536813005898
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AT royparags 2amino7methyl4oxidopteridine6carboxylatok3o4n5o6ethane12diaminek2nn1himidazolekn3nickeliidihydrate