Diaqua­bis­[bis­(pyrazin-2-yl) sulfide-κN (4)]bis­(thio­cyanato-κN)iron(II) monohydrate

In the title compound [Fe(NCS)(2)(C(8)H(6)N(4)S)(2)(H(2)O)(2)]·H(2)O, the Fe(II) cation is coordinated by two N-bonded thio­cyanate anions, two N (4)-bonded bis­(pyrazin-2-yl) sulfide ligands and two water mol­ecules in an slightly distorted octa­hedral geometry. The Fe(II) cation is located on a ce...

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Detalles Bibliográficos
Autores principales: Wöhlert, Susanne, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629478/
https://www.ncbi.nlm.nih.gov/pubmed/23633996
http://dx.doi.org/10.1107/S1600536813006314
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author Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_facet Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_sort Wöhlert, Susanne
collection PubMed
description In the title compound [Fe(NCS)(2)(C(8)H(6)N(4)S)(2)(H(2)O)(2)]·H(2)O, the Fe(II) cation is coordinated by two N-bonded thio­cyanate anions, two N (4)-bonded bis­(pyrazin-2-yl) sulfide ligands and two water mol­ecules in an slightly distorted octa­hedral geometry. The Fe(II) cation is located on a center of inversion and the lattice water mol­ecule on a twofold rotation axis. The thio­cyanate anions, the coordinating water mol­ecules and the sulfide ligands occupy general positions. The complex mol­ecules and lattice water mol­ecules are linked into a three-dimensional network by O—H—N and O—H⋯O hydrogen bonds.
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spelling pubmed-36294782013-04-30 Diaqua­bis­[bis­(pyrazin-2-yl) sulfide-κN (4)]bis­(thio­cyanato-κN)iron(II) monohydrate Wöhlert, Susanne Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound [Fe(NCS)(2)(C(8)H(6)N(4)S)(2)(H(2)O)(2)]·H(2)O, the Fe(II) cation is coordinated by two N-bonded thio­cyanate anions, two N (4)-bonded bis­(pyrazin-2-yl) sulfide ligands and two water mol­ecules in an slightly distorted octa­hedral geometry. The Fe(II) cation is located on a center of inversion and the lattice water mol­ecule on a twofold rotation axis. The thio­cyanate anions, the coordinating water mol­ecules and the sulfide ligands occupy general positions. The complex mol­ecules and lattice water mol­ecules are linked into a three-dimensional network by O—H—N and O—H⋯O hydrogen bonds. International Union of Crystallography 2013-03-09 /pmc/articles/PMC3629478/ /pubmed/23633996 http://dx.doi.org/10.1107/S1600536813006314 Text en © Wöhlert et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wöhlert, Susanne
Jess, Inke
Näther, Christian
Diaqua­bis­[bis­(pyrazin-2-yl) sulfide-κN (4)]bis­(thio­cyanato-κN)iron(II) monohydrate
title Diaqua­bis­[bis­(pyrazin-2-yl) sulfide-κN (4)]bis­(thio­cyanato-κN)iron(II) monohydrate
title_full Diaqua­bis­[bis­(pyrazin-2-yl) sulfide-κN (4)]bis­(thio­cyanato-κN)iron(II) monohydrate
title_fullStr Diaqua­bis­[bis­(pyrazin-2-yl) sulfide-κN (4)]bis­(thio­cyanato-κN)iron(II) monohydrate
title_full_unstemmed Diaqua­bis­[bis­(pyrazin-2-yl) sulfide-κN (4)]bis­(thio­cyanato-κN)iron(II) monohydrate
title_short Diaqua­bis­[bis­(pyrazin-2-yl) sulfide-κN (4)]bis­(thio­cyanato-κN)iron(II) monohydrate
title_sort diaqua­bis­[bis­(pyrazin-2-yl) sulfide-κn (4)]bis­(thio­cyanato-κn)iron(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629478/
https://www.ncbi.nlm.nih.gov/pubmed/23633996
http://dx.doi.org/10.1107/S1600536813006314
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AT natherchristian diaquabisbispyrazin2ylsulfidekn4bisthiocyanatoknironiimonohydrate

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