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catena-Poly[[[diaqua(tetramethylethylenediamine-κ(2) N,N′)nickel(II)]-μ-sulfato-κ(2) O:O′] monohydrate]
The title compound, {[Ni(SO(4))(C(6)H(16)N(2))(H(2)O)(2)]·H(2)O}(n), contains a Ni(II) atom that is coordinated nearly octahedrally by a chelating tetraethylenediamine (tmeda) ligand, two water molecules in a cis arrangement and two O atoms of two sulfate anions in a trans arrangement. The sulfa...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629479/ https://www.ncbi.nlm.nih.gov/pubmed/23633997 http://dx.doi.org/10.1107/S1600536813006557 |
Sumario: | The title compound, {[Ni(SO(4))(C(6)H(16)N(2))(H(2)O)(2)]·H(2)O}(n), contains a Ni(II) atom that is coordinated nearly octahedrally by a chelating tetraethylenediamine (tmeda) ligand, two water molecules in a cis arrangement and two O atoms of two sulfate anions in a trans arrangement. The sulfate anions act as μ(2)-bridging ligands leading to a chain structure of alternating NiO(4)N(2) octahedra and SO(4) tetrahedra parallel to [001]. The polymeric chains are linked by O—H⋯O hydrogen bonds between coordinating water molecules and sulfate anions to give double strands. There is a lattice water molecule which is also involved in O—H⋯O hydrogen bonding between adjacent [Ni(SO(4))(tmeda)(H(2)O)(2)] chains. |
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