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catena-Poly[[[diaqua­(tetra­methyl­ethylenediamine-κ(2) N,N′)nickel(II)]-μ-sulfato-κ(2) O:O′] monohydrate]

The title compound, {[Ni(SO(4))(C(6)H(16)N(2))(H(2)O)(2)]·H(2)O}(n), contains a Ni(II) atom that is coordinated nearly octa­hedrally by a chelating tetra­ethyl­enediamine (tmeda) ligand, two water mol­ecules in a cis arrangement and two O atoms of two sulfate anions in a trans arrangement. The sulfa...

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Autores principales: Schmidt, Guntram, Merzweiler, Kurt
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629479/
https://www.ncbi.nlm.nih.gov/pubmed/23633997
http://dx.doi.org/10.1107/S1600536813006557
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author Schmidt, Guntram
Merzweiler, Kurt
author_facet Schmidt, Guntram
Merzweiler, Kurt
author_sort Schmidt, Guntram
collection PubMed
description The title compound, {[Ni(SO(4))(C(6)H(16)N(2))(H(2)O)(2)]·H(2)O}(n), contains a Ni(II) atom that is coordinated nearly octa­hedrally by a chelating tetra­ethyl­enediamine (tmeda) ligand, two water mol­ecules in a cis arrangement and two O atoms of two sulfate anions in a trans arrangement. The sulfate anions act as μ(2)-bridging ligands leading to a chain structure of alternating NiO(4)N(2) octa­hedra and SO(4) tetra­hedra parallel to [001]. The polymeric chains are linked by O—H⋯O hydrogen bonds between coordinating water mol­ecules and sulfate anions to give double strands. There is a lattice water mol­ecule which is also involved in O—H⋯O hydrogen bonding between adjacent [Ni(SO(4))(tmeda)(H(2)O)(2)] chains.
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spelling pubmed-36294792013-04-30 catena-Poly[[[diaqua­(tetra­methyl­ethylenediamine-κ(2) N,N′)nickel(II)]-μ-sulfato-κ(2) O:O′] monohydrate] Schmidt, Guntram Merzweiler, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Ni(SO(4))(C(6)H(16)N(2))(H(2)O)(2)]·H(2)O}(n), contains a Ni(II) atom that is coordinated nearly octa­hedrally by a chelating tetra­ethyl­enediamine (tmeda) ligand, two water mol­ecules in a cis arrangement and two O atoms of two sulfate anions in a trans arrangement. The sulfate anions act as μ(2)-bridging ligands leading to a chain structure of alternating NiO(4)N(2) octa­hedra and SO(4) tetra­hedra parallel to [001]. The polymeric chains are linked by O—H⋯O hydrogen bonds between coordinating water mol­ecules and sulfate anions to give double strands. There is a lattice water mol­ecule which is also involved in O—H⋯O hydrogen bonding between adjacent [Ni(SO(4))(tmeda)(H(2)O)(2)] chains. International Union of Crystallography 2013-03-13 /pmc/articles/PMC3629479/ /pubmed/23633997 http://dx.doi.org/10.1107/S1600536813006557 Text en © Schmidt and Merzweiler 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Schmidt, Guntram
Merzweiler, Kurt
catena-Poly[[[diaqua­(tetra­methyl­ethylenediamine-κ(2) N,N′)nickel(II)]-μ-sulfato-κ(2) O:O′] monohydrate]
title catena-Poly[[[diaqua­(tetra­methyl­ethylenediamine-κ(2) N,N′)nickel(II)]-μ-sulfato-κ(2) O:O′] monohydrate]
title_full catena-Poly[[[diaqua­(tetra­methyl­ethylenediamine-κ(2) N,N′)nickel(II)]-μ-sulfato-κ(2) O:O′] monohydrate]
title_fullStr catena-Poly[[[diaqua­(tetra­methyl­ethylenediamine-κ(2) N,N′)nickel(II)]-μ-sulfato-κ(2) O:O′] monohydrate]
title_full_unstemmed catena-Poly[[[diaqua­(tetra­methyl­ethylenediamine-κ(2) N,N′)nickel(II)]-μ-sulfato-κ(2) O:O′] monohydrate]
title_short catena-Poly[[[diaqua­(tetra­methyl­ethylenediamine-κ(2) N,N′)nickel(II)]-μ-sulfato-κ(2) O:O′] monohydrate]
title_sort catena-poly[[[diaqua­(tetra­methyl­ethylenediamine-κ(2) n,n′)nickel(ii)]-μ-sulfato-κ(2) o:o′] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629479/
https://www.ncbi.nlm.nih.gov/pubmed/23633997
http://dx.doi.org/10.1107/S1600536813006557
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