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catena-Poly[[[diaqua(tetramethylethylenediamine-κ(2) N,N′)nickel(II)]-μ-sulfato-κ(2) O:O′] monohydrate]
The title compound, {[Ni(SO(4))(C(6)H(16)N(2))(H(2)O)(2)]·H(2)O}(n), contains a Ni(II) atom that is coordinated nearly octahedrally by a chelating tetraethylenediamine (tmeda) ligand, two water molecules in a cis arrangement and two O atoms of two sulfate anions in a trans arrangement. The sulfa...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629479/ https://www.ncbi.nlm.nih.gov/pubmed/23633997 http://dx.doi.org/10.1107/S1600536813006557 |
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author | Schmidt, Guntram Merzweiler, Kurt |
author_facet | Schmidt, Guntram Merzweiler, Kurt |
author_sort | Schmidt, Guntram |
collection | PubMed |
description | The title compound, {[Ni(SO(4))(C(6)H(16)N(2))(H(2)O)(2)]·H(2)O}(n), contains a Ni(II) atom that is coordinated nearly octahedrally by a chelating tetraethylenediamine (tmeda) ligand, two water molecules in a cis arrangement and two O atoms of two sulfate anions in a trans arrangement. The sulfate anions act as μ(2)-bridging ligands leading to a chain structure of alternating NiO(4)N(2) octahedra and SO(4) tetrahedra parallel to [001]. The polymeric chains are linked by O—H⋯O hydrogen bonds between coordinating water molecules and sulfate anions to give double strands. There is a lattice water molecule which is also involved in O—H⋯O hydrogen bonding between adjacent [Ni(SO(4))(tmeda)(H(2)O)(2)] chains. |
format | Online Article Text |
id | pubmed-3629479 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36294792013-04-30 catena-Poly[[[diaqua(tetramethylethylenediamine-κ(2) N,N′)nickel(II)]-μ-sulfato-κ(2) O:O′] monohydrate] Schmidt, Guntram Merzweiler, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Ni(SO(4))(C(6)H(16)N(2))(H(2)O)(2)]·H(2)O}(n), contains a Ni(II) atom that is coordinated nearly octahedrally by a chelating tetraethylenediamine (tmeda) ligand, two water molecules in a cis arrangement and two O atoms of two sulfate anions in a trans arrangement. The sulfate anions act as μ(2)-bridging ligands leading to a chain structure of alternating NiO(4)N(2) octahedra and SO(4) tetrahedra parallel to [001]. The polymeric chains are linked by O—H⋯O hydrogen bonds between coordinating water molecules and sulfate anions to give double strands. There is a lattice water molecule which is also involved in O—H⋯O hydrogen bonding between adjacent [Ni(SO(4))(tmeda)(H(2)O)(2)] chains. International Union of Crystallography 2013-03-13 /pmc/articles/PMC3629479/ /pubmed/23633997 http://dx.doi.org/10.1107/S1600536813006557 Text en © Schmidt and Merzweiler 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Schmidt, Guntram Merzweiler, Kurt catena-Poly[[[diaqua(tetramethylethylenediamine-κ(2) N,N′)nickel(II)]-μ-sulfato-κ(2) O:O′] monohydrate] |
title |
catena-Poly[[[diaqua(tetramethylethylenediamine-κ(2)
N,N′)nickel(II)]-μ-sulfato-κ(2)
O:O′] monohydrate] |
title_full |
catena-Poly[[[diaqua(tetramethylethylenediamine-κ(2)
N,N′)nickel(II)]-μ-sulfato-κ(2)
O:O′] monohydrate] |
title_fullStr |
catena-Poly[[[diaqua(tetramethylethylenediamine-κ(2)
N,N′)nickel(II)]-μ-sulfato-κ(2)
O:O′] monohydrate] |
title_full_unstemmed |
catena-Poly[[[diaqua(tetramethylethylenediamine-κ(2)
N,N′)nickel(II)]-μ-sulfato-κ(2)
O:O′] monohydrate] |
title_short |
catena-Poly[[[diaqua(tetramethylethylenediamine-κ(2)
N,N′)nickel(II)]-μ-sulfato-κ(2)
O:O′] monohydrate] |
title_sort | catena-poly[[[diaqua(tetramethylethylenediamine-κ(2)
n,n′)nickel(ii)]-μ-sulfato-κ(2)
o:o′] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629479/ https://www.ncbi.nlm.nih.gov/pubmed/23633997 http://dx.doi.org/10.1107/S1600536813006557 |
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