[1,2-Bis(diisopropyl­phosphan­yl)ethane-κ(2) P,P′](carbonato-κ(2) O,O′)nickel(II)

In the crystal of the title compound, [Ni(CO(3))(C(14)H(32)P(2))], the metal center in each of three independent mol­ecules shows slight tetra­hedral distortion from ideal square-planar coordination geometry, with angles between the normals to the planes defined by the cis-P—Ni—P and cis-O—Ni—O frag...

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Detalles Bibliográficos
Autores principales: Morales-Becerril, Illan, Flores-Alamo, Marcos, Garcia, Juventino J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629481/
https://www.ncbi.nlm.nih.gov/pubmed/23633999
http://dx.doi.org/10.1107/S1600536813006521
Descripción
Sumario:In the crystal of the title compound, [Ni(CO(3))(C(14)H(32)P(2))], the metal center in each of three independent mol­ecules shows slight tetra­hedral distortion from ideal square-planar coordination geometry, with angles between the normals to the planes defined by the cis-P—Ni—P and cis-O—Ni—O fragments of 3.92 (17), 0.70 (16) and 2.17 (14)° in the three mol­ecules. In the crystal, there are inter­molecular C—H⋯O hydrogen bonds that show a laminar growth in the ab plane.

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