[1,2-Bis(diisopropyl­phosphan­yl)ethane-κ(2) P,P′](carbonato-κ(2) O,O′)nickel(II)

In the crystal of the title compound, [Ni(CO(3))(C(14)H(32)P(2))], the metal center in each of three independent mol­ecules shows slight tetra­hedral distortion from ideal square-planar coordination geometry, with angles between the normals to the planes defined by the cis-P—Ni—P and cis-O—Ni—O frag...

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Detalles Bibliográficos
Autores principales: Morales-Becerril, Illan, Flores-Alamo, Marcos, Garcia, Juventino J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629481/
https://www.ncbi.nlm.nih.gov/pubmed/23633999
http://dx.doi.org/10.1107/S1600536813006521
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author Morales-Becerril, Illan
Flores-Alamo, Marcos
Garcia, Juventino J.
author_facet Morales-Becerril, Illan
Flores-Alamo, Marcos
Garcia, Juventino J.
author_sort Morales-Becerril, Illan
collection PubMed
description In the crystal of the title compound, [Ni(CO(3))(C(14)H(32)P(2))], the metal center in each of three independent mol­ecules shows slight tetra­hedral distortion from ideal square-planar coordination geometry, with angles between the normals to the planes defined by the cis-P—Ni—P and cis-O—Ni—O fragments of 3.92 (17), 0.70 (16) and 2.17 (14)° in the three mol­ecules. In the crystal, there are inter­molecular C—H⋯O hydrogen bonds that show a laminar growth in the ab plane.
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spelling pubmed-36294812013-04-30 [1,2-Bis(diisopropyl­phosphan­yl)ethane-κ(2) P,P′](carbonato-κ(2) O,O′)nickel(II) Morales-Becerril, Illan Flores-Alamo, Marcos Garcia, Juventino J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal of the title compound, [Ni(CO(3))(C(14)H(32)P(2))], the metal center in each of three independent mol­ecules shows slight tetra­hedral distortion from ideal square-planar coordination geometry, with angles between the normals to the planes defined by the cis-P—Ni—P and cis-O—Ni—O fragments of 3.92 (17), 0.70 (16) and 2.17 (14)° in the three mol­ecules. In the crystal, there are inter­molecular C—H⋯O hydrogen bonds that show a laminar growth in the ab plane. International Union of Crystallography 2013-03-13 /pmc/articles/PMC3629481/ /pubmed/23633999 http://dx.doi.org/10.1107/S1600536813006521 Text en © Morales-Becerril et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Morales-Becerril, Illan
Flores-Alamo, Marcos
Garcia, Juventino J.
[1,2-Bis(diisopropyl­phosphan­yl)ethane-κ(2) P,P′](carbonato-κ(2) O,O′)nickel(II)
title [1,2-Bis(diisopropyl­phosphan­yl)ethane-κ(2) P,P′](carbonato-κ(2) O,O′)nickel(II)
title_full [1,2-Bis(diisopropyl­phosphan­yl)ethane-κ(2) P,P′](carbonato-κ(2) O,O′)nickel(II)
title_fullStr [1,2-Bis(diisopropyl­phosphan­yl)ethane-κ(2) P,P′](carbonato-κ(2) O,O′)nickel(II)
title_full_unstemmed [1,2-Bis(diisopropyl­phosphan­yl)ethane-κ(2) P,P′](carbonato-κ(2) O,O′)nickel(II)
title_short [1,2-Bis(diisopropyl­phosphan­yl)ethane-κ(2) P,P′](carbonato-κ(2) O,O′)nickel(II)
title_sort [1,2-bis(diisopropyl­phosphan­yl)ethane-κ(2) p,p′](carbonato-κ(2) o,o′)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629481/
https://www.ncbi.nlm.nih.gov/pubmed/23633999
http://dx.doi.org/10.1107/S1600536813006521
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