cis-Chlorido(methyl­amine)­bis­(propane-1,3-diamine)­cobalt(III) dichloride monohydrate

In the title compound, [CoCl(CH(5)N)(C(3)H(10)N(2))(2)]Cl(2)·H(2)O, the Co(III) ion has an octa­hedral coordination environment and is surrounded by four N atoms of two propane-1,3-diamine ligands in the equatorial plane, with another N atom of the methylamine ligand and a Cl atom occupying the axia...

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Detalles Bibliográficos
Autores principales: Maheshwaran, Velusamy, Manjunathan, Munisamy, Anbalagan, Krishnamoorthy, Thiruselvam, Viswanathan, Ponnuswamy, Mondikalipudur Nanjappagounder
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629484/
https://www.ncbi.nlm.nih.gov/pubmed/23634002
http://dx.doi.org/10.1107/S1600536813006442
Descripción
Sumario:In the title compound, [CoCl(CH(5)N)(C(3)H(10)N(2))(2)]Cl(2)·H(2)O, the Co(III) ion has an octa­hedral coordination environment and is surrounded by four N atoms of two propane-1,3-diamine ligands in the equatorial plane, with another N atom of the methylamine ligand and a Cl atom occupying the axial positions. The crystal packing is stabilized by inter­molecular N—H⋯O, N—H⋯Cl, and O—H⋯Cl inter­actions, generating a three-dimensional network.

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