cis-Chlorido(methyl­amine)­bis­(propane-1,3-diamine)­cobalt(III) dichloride monohydrate

In the title compound, [CoCl(CH(5)N)(C(3)H(10)N(2))(2)]Cl(2)·H(2)O, the Co(III) ion has an octa­hedral coordination environment and is surrounded by four N atoms of two propane-1,3-diamine ligands in the equatorial plane, with another N atom of the methylamine ligand and a Cl atom occupying the axia...

Descripción completa

Detalles Bibliográficos
Autores principales: Maheshwaran, Velusamy, Manjunathan, Munisamy, Anbalagan, Krishnamoorthy, Thiruselvam, Viswanathan, Ponnuswamy, Mondikalipudur Nanjappagounder
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629484/
https://www.ncbi.nlm.nih.gov/pubmed/23634002
http://dx.doi.org/10.1107/S1600536813006442
_version_ 1782266588728131584
author Maheshwaran, Velusamy
Manjunathan, Munisamy
Anbalagan, Krishnamoorthy
Thiruselvam, Viswanathan
Ponnuswamy, Mondikalipudur Nanjappagounder
author_facet Maheshwaran, Velusamy
Manjunathan, Munisamy
Anbalagan, Krishnamoorthy
Thiruselvam, Viswanathan
Ponnuswamy, Mondikalipudur Nanjappagounder
author_sort Maheshwaran, Velusamy
collection PubMed
description In the title compound, [CoCl(CH(5)N)(C(3)H(10)N(2))(2)]Cl(2)·H(2)O, the Co(III) ion has an octa­hedral coordination environment and is surrounded by four N atoms of two propane-1,3-diamine ligands in the equatorial plane, with another N atom of the methylamine ligand and a Cl atom occupying the axial positions. The crystal packing is stabilized by inter­molecular N—H⋯O, N—H⋯Cl, and O—H⋯Cl inter­actions, generating a three-dimensional network.
format Online
Article
Text
id pubmed-3629484
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-36294842013-04-30 cis-Chlorido(methyl­amine)­bis­(propane-1,3-diamine)­cobalt(III) dichloride monohydrate Maheshwaran, Velusamy Manjunathan, Munisamy Anbalagan, Krishnamoorthy Thiruselvam, Viswanathan Ponnuswamy, Mondikalipudur Nanjappagounder Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(CH(5)N)(C(3)H(10)N(2))(2)]Cl(2)·H(2)O, the Co(III) ion has an octa­hedral coordination environment and is surrounded by four N atoms of two propane-1,3-diamine ligands in the equatorial plane, with another N atom of the methylamine ligand and a Cl atom occupying the axial positions. The crystal packing is stabilized by inter­molecular N—H⋯O, N—H⋯Cl, and O—H⋯Cl inter­actions, generating a three-dimensional network. International Union of Crystallography 2013-03-13 /pmc/articles/PMC3629484/ /pubmed/23634002 http://dx.doi.org/10.1107/S1600536813006442 Text en © Maheshwaran et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Maheshwaran, Velusamy
Manjunathan, Munisamy
Anbalagan, Krishnamoorthy
Thiruselvam, Viswanathan
Ponnuswamy, Mondikalipudur Nanjappagounder
cis-Chlorido(methyl­amine)­bis­(propane-1,3-diamine)­cobalt(III) dichloride monohydrate
title cis-Chlorido(methyl­amine)­bis­(propane-1,3-diamine)­cobalt(III) dichloride monohydrate
title_full cis-Chlorido(methyl­amine)­bis­(propane-1,3-diamine)­cobalt(III) dichloride monohydrate
title_fullStr cis-Chlorido(methyl­amine)­bis­(propane-1,3-diamine)­cobalt(III) dichloride monohydrate
title_full_unstemmed cis-Chlorido(methyl­amine)­bis­(propane-1,3-diamine)­cobalt(III) dichloride monohydrate
title_short cis-Chlorido(methyl­amine)­bis­(propane-1,3-diamine)­cobalt(III) dichloride monohydrate
title_sort cis-chlorido(methyl­amine)­bis­(propane-1,3-diamine)­cobalt(iii) dichloride monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629484/
https://www.ncbi.nlm.nih.gov/pubmed/23634002
http://dx.doi.org/10.1107/S1600536813006442
work_keys_str_mv AT maheshwaranvelusamy cischloridomethylaminebispropane13diaminecobaltiiidichloridemonohydrate
AT manjunathanmunisamy cischloridomethylaminebispropane13diaminecobaltiiidichloridemonohydrate
AT anbalagankrishnamoorthy cischloridomethylaminebispropane13diaminecobaltiiidichloridemonohydrate
AT thiruselvamviswanathan cischloridomethylaminebispropane13diaminecobaltiiidichloridemonohydrate
AT ponnuswamymondikalipudurnanjappagounder cischloridomethylaminebispropane13diaminecobaltiiidichloridemonohydrate

Ejemplares similares