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Poly[diaquabis(μ-4,4′-bipyridine-κ(2) N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ(2) O:O′)dicobalt(II)]
In the title compound, [Co(2)(SO(4))(2)(C(10)H(8)N(2))(2)(C(2)H(6)O(2))(2)(H(2)O)(2)](n), there are two crystallographically independent Co(II) ions, each of which lies on a twofold rotation axis and has a slightly distorted octahedral environment. One Co(II) ion is coordinated by two N atoms from...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629485/ https://www.ncbi.nlm.nih.gov/pubmed/23634003 http://dx.doi.org/10.1107/S1600536813006685 |
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author | Zhong, Kai-Long |
author_facet | Zhong, Kai-Long |
author_sort | Zhong, Kai-Long |
collection | PubMed |
description | In the title compound, [Co(2)(SO(4))(2)(C(10)H(8)N(2))(2)(C(2)H(6)O(2))(2)(H(2)O)(2)](n), there are two crystallographically independent Co(II) ions, each of which lies on a twofold rotation axis and has a slightly distorted octahedral environment. One Co(II) ion is coordinated by two N atoms from two bridging 4,4′-bipyridine (4,4′-bipy) ligands, two O atoms from two sulfate ions and two O atoms from aqua ligands. The second Co(II) ion is similar but with ethane-1,2-diol ligands in place of water molecules. The sulfate anions act as bridging ligands to link two adjacent Co(II) ions together, leading to the formation of linear ⋯Co1Co2Co1Co2⋯chains along the a axis. Adjacent chains are further bridged by 4,4′-bipy ligands, which are also located on the twofold rotation axis, resulting in a two-dimensional layered polymer extending parallel to (001). In the crystal, the layers are linked by extensive O—H⋯O hydrogen-bonding interactions involving the O atoms of the water molecules and ethane-1,2-diol molecules, resulting in a three-dimensional supramolecular network. |
format | Online Article Text |
id | pubmed-3629485 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36294852013-04-30 Poly[diaquabis(μ-4,4′-bipyridine-κ(2) N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ(2) O:O′)dicobalt(II)] Zhong, Kai-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(2)(SO(4))(2)(C(10)H(8)N(2))(2)(C(2)H(6)O(2))(2)(H(2)O)(2)](n), there are two crystallographically independent Co(II) ions, each of which lies on a twofold rotation axis and has a slightly distorted octahedral environment. One Co(II) ion is coordinated by two N atoms from two bridging 4,4′-bipyridine (4,4′-bipy) ligands, two O atoms from two sulfate ions and two O atoms from aqua ligands. The second Co(II) ion is similar but with ethane-1,2-diol ligands in place of water molecules. The sulfate anions act as bridging ligands to link two adjacent Co(II) ions together, leading to the formation of linear ⋯Co1Co2Co1Co2⋯chains along the a axis. Adjacent chains are further bridged by 4,4′-bipy ligands, which are also located on the twofold rotation axis, resulting in a two-dimensional layered polymer extending parallel to (001). In the crystal, the layers are linked by extensive O—H⋯O hydrogen-bonding interactions involving the O atoms of the water molecules and ethane-1,2-diol molecules, resulting in a three-dimensional supramolecular network. International Union of Crystallography 2013-03-16 /pmc/articles/PMC3629485/ /pubmed/23634003 http://dx.doi.org/10.1107/S1600536813006685 Text en © Kai-Long Zhong 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhong, Kai-Long Poly[diaquabis(μ-4,4′-bipyridine-κ(2) N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ(2) O:O′)dicobalt(II)] |
title | Poly[diaquabis(μ-4,4′-bipyridine-κ(2)
N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ(2)
O:O′)dicobalt(II)] |
title_full | Poly[diaquabis(μ-4,4′-bipyridine-κ(2)
N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ(2)
O:O′)dicobalt(II)] |
title_fullStr | Poly[diaquabis(μ-4,4′-bipyridine-κ(2)
N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ(2)
O:O′)dicobalt(II)] |
title_full_unstemmed | Poly[diaquabis(μ-4,4′-bipyridine-κ(2)
N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ(2)
O:O′)dicobalt(II)] |
title_short | Poly[diaquabis(μ-4,4′-bipyridine-κ(2)
N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ(2)
O:O′)dicobalt(II)] |
title_sort | poly[diaquabis(μ-4,4′-bipyridine-κ(2)
n:n′)bis(ethane-1,2-diol-κo)bis(μ-sulfato-κ(2)
o:o′)dicobalt(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629485/ https://www.ncbi.nlm.nih.gov/pubmed/23634003 http://dx.doi.org/10.1107/S1600536813006685 |
work_keys_str_mv | AT zhongkailong polydiaquabism44bipyridinek2nnbisethane12diolkobismsulfatok2oodicobaltii |