cis-Dichloridobis(ethyl methyl sulfide-κS)oxidovanadium(IV)

The mononuclear title complex, [VCl(2)O(C(3)H(8)S)(2)], features a V(IV)=O double bond [1.5845 (15) Å] in an overall trigonal–bipyramidal coordination environment defined by two Cl(−) and the S atoms of two (CH(3)CH(2))(CH(3))S ligands. In the crystal, pairs of mol­ecules form centrosymmetric dimers...

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Detalles Bibliográficos
Autores principales: Matsuura, Masatoshi, Fujihara, Takashi, Nagasawa, Akira
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629486/
https://www.ncbi.nlm.nih.gov/pubmed/23634004
http://dx.doi.org/10.1107/S1600536813006703
Descripción
Sumario:The mononuclear title complex, [VCl(2)O(C(3)H(8)S)(2)], features a V(IV)=O double bond [1.5845 (15) Å] in an overall trigonal–bipyramidal coordination environment defined by two Cl(−) and the S atoms of two (CH(3)CH(2))(CH(3))S ligands. In the crystal, pairs of mol­ecules form centrosymmetric dimers via C—H⋯O hydrogen bonds between the methyl C—H group and the oxidovanadium O atom of a neighbouring mol­ecule.

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