cis-Dichloridobis(ethyl methyl sulfide-κS)oxidovanadium(IV)

The mononuclear title complex, [VCl(2)O(C(3)H(8)S)(2)], features a V(IV)=O double bond [1.5845 (15) Å] in an overall trigonal–bipyramidal coordination environment defined by two Cl(−) and the S atoms of two (CH(3)CH(2))(CH(3))S ligands. In the crystal, pairs of mol­ecules form centrosymmetric dimers...

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Detalles Bibliográficos
Autores principales: Matsuura, Masatoshi, Fujihara, Takashi, Nagasawa, Akira
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629486/
https://www.ncbi.nlm.nih.gov/pubmed/23634004
http://dx.doi.org/10.1107/S1600536813006703
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author Matsuura, Masatoshi
Fujihara, Takashi
Nagasawa, Akira
author_facet Matsuura, Masatoshi
Fujihara, Takashi
Nagasawa, Akira
author_sort Matsuura, Masatoshi
collection PubMed
description The mononuclear title complex, [VCl(2)O(C(3)H(8)S)(2)], features a V(IV)=O double bond [1.5845 (15) Å] in an overall trigonal–bipyramidal coordination environment defined by two Cl(−) and the S atoms of two (CH(3)CH(2))(CH(3))S ligands. In the crystal, pairs of mol­ecules form centrosymmetric dimers via C—H⋯O hydrogen bonds between the methyl C—H group and the oxidovanadium O atom of a neighbouring mol­ecule.
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spelling pubmed-36294862013-04-30 cis-Dichloridobis(ethyl methyl sulfide-κS)oxidovanadium(IV) Matsuura, Masatoshi Fujihara, Takashi Nagasawa, Akira Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mononuclear title complex, [VCl(2)O(C(3)H(8)S)(2)], features a V(IV)=O double bond [1.5845 (15) Å] in an overall trigonal–bipyramidal coordination environment defined by two Cl(−) and the S atoms of two (CH(3)CH(2))(CH(3))S ligands. In the crystal, pairs of mol­ecules form centrosymmetric dimers via C—H⋯O hydrogen bonds between the methyl C—H group and the oxidovanadium O atom of a neighbouring mol­ecule. International Union of Crystallography 2013-03-16 /pmc/articles/PMC3629486/ /pubmed/23634004 http://dx.doi.org/10.1107/S1600536813006703 Text en © Matsuura et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Matsuura, Masatoshi
Fujihara, Takashi
Nagasawa, Akira
cis-Dichloridobis(ethyl methyl sulfide-κS)oxidovanadium(IV)
title cis-Dichloridobis(ethyl methyl sulfide-κS)oxidovanadium(IV)
title_full cis-Dichloridobis(ethyl methyl sulfide-κS)oxidovanadium(IV)
title_fullStr cis-Dichloridobis(ethyl methyl sulfide-κS)oxidovanadium(IV)
title_full_unstemmed cis-Dichloridobis(ethyl methyl sulfide-κS)oxidovanadium(IV)
title_short cis-Dichloridobis(ethyl methyl sulfide-κS)oxidovanadium(IV)
title_sort cis-dichloridobis(ethyl methyl sulfide-κs)oxidovanadium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629486/
https://www.ncbi.nlm.nih.gov/pubmed/23634004
http://dx.doi.org/10.1107/S1600536813006703
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